Ma Shuai, Jia Run, Li Yanan, Liu Changyan, Guo Hao
School of Mechanical Engineering, Tianjin University of Commerce, Tianjin 300134, China.
College of Science, North China University of Technology, Beijing 100144, China.
ACS Omega. 2025 Mar 13;10(11):11342-11353. doi: 10.1021/acsomega.4c11179. eCollection 2025 Mar 25.
The solid oxide fuel cell (SOFC) system as green and efficient power-generation equipment needs to match a reasonable system design and parameter sensitivity analysis in different application fields. The complex SOFC system is accompanied by electrochemical, ionic conduction, and mass transport reactions, making it difficult to predict stack performance. In this article, the conceptual design of the electrolyte-supported SOFC with a biogas-fed cogeneration system is carried out. Two system layouts featuring different anode recirculation schemes (hot and cold) and reforming methods under fluctuation fuel types are designed. Based on the above simulation data, three different algorithm models, including long short-term memory (LSTM), one-dimensional convolutional neural network (1DCNN), and integration model, are used to estimate the SOFC response and predict the SOFC voltage under fluctuating fuel inlet conditions with multiple evaluation criteria. The CatBoost integrator effectively combines the characteristics of LSTM and 1DCNN in the spatial and temporal information, breaks the barriers between temporal and nontemporal data, and avoids the suboptimal solution of static fusion, further improving the prediction accuracy and reliability for the cold recirculation plant configuration scheme. The determination coefficient improves from 0.5 to 0.8, the RMSE and MAE index decrease by up to 44%, and the MAPE index decreases by up to 29%. For the hot recirculation scheme, the fusion algorithm also shows better prediction results under strong periodic training data. Thus, the proposed prediction model can effectively evaluate the SOFC system output without conducting additional physical experiments.
固体氧化物燃料电池(SOFC)系统作为绿色高效的发电设备,在不同应用领域需要匹配合理的系统设计和参数敏感性分析。复杂的SOFC系统伴随着电化学、离子传导和质量传输反应,使得预测电池堆性能变得困难。本文对采用沼气联产系统的电解质支撑型SOFC进行了概念设计。设计了两种具有不同阳极再循环方案(热循环和冷循环)以及在燃料类型波动情况下的重整方法的系统布局。基于上述模拟数据,使用包括长短期记忆网络(LSTM)、一维卷积神经网络(1DCNN)和集成模型在内的三种不同算法模型,以多种评估标准来估计SOFC响应并预测燃料入口条件波动下的SOFC电压。CatBoost集成器有效地结合了LSTM和1DCNN在空间和时间信息方面的特点,打破了时间和非时间数据之间的障碍,避免了静态融合的次优解,进一步提高了冷再循环装置配置方案的预测准确性和可靠性。决定系数从0.5提高到0.8,RMSE和MAE指标最多降低44%,MAPE指标最多降低29%。对于热再循环方案,在强周期性训练数据下,融合算法也显示出更好的预测结果。因此,所提出的预测模型无需进行额外的物理实验就能有效地评估SOFC系统输出。