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磷石膏改良土壤并促进作物生长:一种利用固体废物资源的有效措施。

Phosphogypsum improves soil and benefits crop growth: An effective measure for utilizing solid waste resources.

作者信息

Gao Liu, Li Runhe, Yang Dejian, Bao Li, Zhang Naiming

机构信息

College of Resources and Environment, Yunnan Agricultural University, Kunming, 650201, China.

Yunnan Soil Fertility and Pollution Restoration Laboratory, Yunnan Agricultural University, Kunming, 650201, China.

出版信息

Sci Rep. 2025 Apr 7;15(1):11827. doi: 10.1038/s41598-025-97216-8.

Abstract

The utilization rate of phosphogypsum (PG) is currently low, and prolonged storage poses environmental pollution. Therefore, there is an urgent need to promote resource-efficient utilization. This study investigated the alterations in the characteristics of modified PG artificial soil (MPG-soil) and their influence on buckwheat (Fagopyrum esculentum Moench) growth using hierarchical land reclamation technique (HLRT) and integrated land reclamation technique (ILRT). The results demonstrated that MPG-soil reduced bulk density (3.8-6.9%), enhanced moisture content (up to 22%), and improved enzymatic activity. HLRT achieved superior phosphorus mineralization (7.53 U/g S-NP activity) and increased buckwheat yield by 130.6% over controls. Despite elevated soil salinity, MPG amendments restricted heavy metal accumulation in grains (BCF < 0.3), though Pb levels exceeded national standards due to background contamination. Nutrient dynamics revealed increased phosphorus availability but reduced organic matter, necessitating supplemental fertilization. The Nemerow index confirmed all treatments as "Safe and Clean", while principal component analysis highlighted HLRT's efficacy in balancing soil structure and fertility. Proline accumulation in high-PG treatments indicated adaptive stress responses. MPG-soil effectively contained heavy metal migration, ensuring agricultural product safety. This study assessed the potential of PG for land reclamation, and provided guidelines for its safe utilization in agriculture.

摘要

目前磷石膏(PG)的利用率较低,长期储存会造成环境污染。因此,迫切需要促进其资源高效利用。本研究采用分层土地复垦技术(HLRT)和综合土地复垦技术(ILRT),研究了改良磷石膏人工土壤(MPG-土壤)特性的变化及其对荞麦(苦荞麦)生长的影响。结果表明,MPG-土壤降低了容重(3.8-6.9%),提高了含水量(高达22%),并改善了酶活性。HLRT实现了更高的磷矿化作用(7.53 U/g S-NP活性),荞麦产量比对照提高了130.6%。尽管土壤盐分升高,但MPG改良剂限制了重金属在谷物中的积累(生物富集系数<0.3),不过由于背景污染,铅含量超过了国家标准。养分动态表明磷有效性增加,但有机质减少,因此需要补充施肥。内梅罗指数证实所有处理均为“安全清洁”,而主成分分析突出了HLRT在平衡土壤结构和肥力方面的功效。高PG处理中脯氨酸的积累表明存在适应性应激反应。MPG-土壤有效地抑制了重金属迁移,确保了农产品安全。本研究评估了磷石膏用于土地复垦的潜力,并为其在农业中的安全利用提供了指导。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a87/11977224/2a15f98fd516/41598_2025_97216_Fig1_HTML.jpg

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