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基于2-氨基-[(香豆素-3-基)-4-(4-(二苯胺基)苯基]烟腈荧光染料的染料敏化太阳能电池

Dye Sensitized Solar Cells Based on 2-Amino-[(Coumarin-3-yl)-4-(4-(Diphenylamino)Phenyl]nicotinonitrile Fluorescent Dyes.

作者信息

Mavazzan Ahmedraza, Mendhe Avinash C, Madar Suresh F, Kamble Ravindra R, Sankapal Babasaheb R, Nadoni Vishwa B, Bayannavar Praveen K, Pasha K M Mussuvir

机构信息

Department of Studies in Chemistry, Karnatak University, Pavate Nagar, Dharwad, Karnataka, 580003, India.

Nanomaterials and Device Laboratory, Department of Physics, Visvesvaraya National Institute of Technology, South Ambazari Road, Nagpur, M.S, 440010, India.

出版信息

J Fluoresc. 2025 Apr 10. doi: 10.1007/s10895-025-04243-9.

Abstract

By introducing novel sensitizer dyes such as ACT, BCT, and SCT, this study seeks to significantly contribute to the field of dye-sensitized solar cells (DSSCs). Modern microwave irradiation has been used to carefully design these dyes. These reaction's outcomes clearly demonstrate how superior this technique is to conventional synthetic approaches. It not only reduces reaction time but also yields better results. A detailed analysis of these novel dyes has demonstrated their superior optical and electrochemical characteristics, which have been validated with the help of Cyclic Voltammetry and UV-Vis spectroscopy. The thorough investigation into solar cell domain involved creation of DSSC devices, where these dyes were used as sensitizers along with Cadmium sulphide Nanowires, as semiconductor material. The results demonstrated a notable increase in the device performance, boosting to 3.67 times the efficiency of bare CdS NW devices. Accompanying these results were Density Functional Theory (DFT) calculations and external quantum efficiency data, pleasantly validating the photovoltaic experiments. This research reveals the fascinating potential of these novel compounds as efficient sensitizers for DSSCs. Furthermore, it confers vital insights into their photovoltaic performance, thereby opening a way to researcher in advancements in solar cell technology.

摘要

通过引入诸如ACT、BCT和SCT等新型敏化染料,本研究旨在为染料敏化太阳能电池(DSSC)领域做出重大贡献。现代微波辐射已被用于精心设计这些染料。这些反应的结果清楚地表明了该技术相对于传统合成方法的优越性。它不仅缩短了反应时间,而且产生了更好的结果。对这些新型染料的详细分析表明了它们优异的光学和电化学特性,这些特性已通过循环伏安法和紫外可见光谱法得到验证。对太阳能电池领域的深入研究涉及到DSSC器件的制作,其中这些染料与硫化镉纳米线一起用作敏化剂,作为半导体材料。结果表明器件性能显著提高,效率提高到裸CdS NW器件的3.67倍。伴随着这些结果的是密度泛函理论(DFT)计算和外部量子效率数据,令人满意地验证了光伏实验。这项研究揭示了这些新型化合物作为DSSC高效敏化剂的迷人潜力。此外,它还提供了关于其光伏性能的重要见解,从而为太阳能电池技术的进步开辟了一条研究途径。

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