Lapčík Lubomír, Vašina Martin, Murtaja Yousef, Sepetcioglu Harun, Lapčíková Barbora, Ovsík Martin, Staněk Michal, Karagöz İdris, Vadanagekar Apurva Shahaji
Department of Physical Chemistry, Faculty of Science, Palacky University, 17. Listopadu 12, 771 46 Olomouc, Czech Republic.
Faculty of Technology, Tomas Bata University in Zlin, Vavreckova 5669, 760 01 Zlin, Czech Republic.
Polymers (Basel). 2025 Mar 27;17(7):909. doi: 10.3390/polym17070909.
This study investigated the mechanical, thermal, and morphological properties of acrylonitrile butadiene styrene (ABS)-based nanocomposites reinforced with different types and concentrations of nanofillers. The uniaxial tensile testing results indicated that Young's modulus () generally decreased with increasing filler content, except at 0.500 w.% filler concentration, where a slight increase in stiffness was observed. A statistically significant interaction between sample type and filler concentration was identified ( = 0.045). Fracture toughness measurements revealed a significant reduction in impact resistance at 1.000 w.% filler concentration, with values dropping by up to 67% compared with neat acrylonitrile butadiene styrene. Dynamic mechanical vibration testing confirmed a decrease in stiffness, as evidenced by a shift of the first resonance frequency () to lower values. Hardness measurements including indentation and Shore D hardness exhibited an increasing trend with rising filler concentration, with statistically significant differences observed at specific concentration levels ( < 0.05). Scanning electron microscopy analysis showed that nanofillers were well dispersed at lower concentrations, but agglomeration began above 0.500 w.%, resulting in void formation and a noticeable decline in mechanical properties. The results suggest that an optimal filler concentration range of 0.250-0.500 w.% offers an ideal balance between enhanced mechanical properties and material integrity.
本研究调查了用不同类型和浓度的纳米填料增强的丙烯腈-丁二烯-苯乙烯(ABS)基纳米复合材料的力学、热学和形态学性能。单轴拉伸试验结果表明,杨氏模量()通常随填料含量的增加而降低,但在填料浓度为0.500 w.%时除外,此时观察到刚度略有增加。确定了样品类型与填料浓度之间存在统计学上显著的相互作用( = 0.045)。断裂韧性测量结果显示,在填料浓度为1.000 w.%时,抗冲击性显著降低,与纯丙烯腈-丁二烯-苯乙烯相比,数值下降高达67%。动态机械振动测试证实了刚度的降低,这由第一共振频率()向较低值的偏移证明。包括压痕硬度和邵氏D硬度在内的硬度测量结果显示,随着填料浓度的增加呈上升趋势,在特定浓度水平下观察到统计学上的显著差异( < 0.05)。扫描电子显微镜分析表明,纳米填料在较低浓度下分散良好,但在高于0.500 w.%时开始团聚,导致形成空隙并使力学性能显著下降。结果表明,0.250 - 0.500 w.%的最佳填料浓度范围在增强力学性能和材料完整性之间提供了理想的平衡。