脒基和二硫纶基硅配合物。
Amidinate- and Dithiolene-Based Silicon Complexes.
作者信息
Wang Yuzhong, Johnson John C, Palmer Kayla G, Wei Pingrong, Adams Earle R, Lahm Mitchell E, Schaefer Henry F, Robinson Gregory H
机构信息
Department of Chemistry and Center for Computational Chemistry, The University of Georgia, Athens, Georgia 30602-2556, United States.
出版信息
Organometallics. 2025 Mar 19;44(7):802-806. doi: 10.1021/acs.organomet.5c00038. eCollection 2025 Apr 14.
Reactions of the amidinato-silylene chloride PhC( BuN)SiCl () with imidazole-based dithione dimer , lithium dithiolene radical , and dithiolate dimer result in the synthesis of a series of silicon complexes -, respectively, containing both amidinato and dithiolene ligands. is the first structurally characterized silicon(II) dithiolene complex. The structural and bonding characteristics of - have been probed by both experimental and theoretical methods.
脒基亚硅基氯代物PhC( BuN)SiCl（）与咪唑基二硫酮二聚体、二硫代烯锂自由基和二硫醇盐二聚体反应，分别合成了一系列同时含有脒基和二硫代烯配体的硅配合物 - 。是首个经结构表征的硅（II）二硫代烯配合物。已通过实验和理论方法对 - 的结构和键合特征进行了探究。
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