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镁渣场扬尘的环境与健康风险评估

Environmental and Health Risk Assessment of Fugitive Dust from Magnesium Slag Yards.

作者信息

Hua Jing, Zhao Yuanchao, Zhang Yuanzheng, Zhu Yining, Liu Chang, Wang Fenghe, Xu Xiaowei, Yu Qi

机构信息

Nanjing Institute of Environmental Science, Ministry of Ecology and Environment of China, Nanjing 210042, China.

School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.

出版信息

Toxics. 2025 Apr 15;13(4):307. doi: 10.3390/toxics13040307.

Abstract

During the natural cooling process of magnesium slag stockpiles in the open air, the phase transformation of gamma-dicalcium silicate (γ-CS) induces a powdering phenomenon, resulting in the generation of a large amount of PM10 and PM2.5 dust. Based on the dust emission model of stockpiles and the Gaussian dispersion model, combined with the Monte Carlo simulation method, this study conducted a quantitative assessment of the environmental risk of heavy metals (Pb, Cd, Hg, As, Cr(VI)) in dust to the surrounding residential areas. The results show that the enrichment degree of heavy metals in PM2.5 is significantly higher than that in PM10. At a downwind distance of 1000 m, the exceedance multiples of Cr(VI), As, and Cd reach 131.5, 23.6, and 51.8 times, respectively. The total carcinogenic risk (9.2 × 10) and total non-carcinogenic hazard quotient (0.15) in the residential area are below the limits, but the contribution rates of As and Cd are relatively high. Sensitivity analysis further reveals that the moisture content of the stockpile, dust removal rate, and distance are the key control parameters affecting the environmental risk. Based on the research findings, it is recommended to increase sprinkling frequency, install windbreak nets, and promote magnesium slag utilization to effectively control dust risks.

摘要

在露天镁渣堆自然冷却过程中,γ-硅酸二钙(γ-CS)的相变引发粉化现象,导致产生大量PM10和PM2.5粉尘。基于堆存粉尘排放模型和高斯扩散模型,结合蒙特卡罗模拟方法,本研究对粉尘中重金属(铅、镉、汞、砷、六价铬)对周边居民区的环境风险进行了定量评估。结果表明,PM2.5中重金属的富集程度显著高于PM10。在1000米的下风向距离处,六价铬、砷和镉的超标倍数分别达到131.5倍、23.6倍和51.8倍。居民区的总致癌风险(9.2×10)和总非致癌危害商(0.15)低于限值,但砷和镉的贡献率相对较高。敏感性分析进一步表明,堆存湿度、除尘率和距离是影响环境风险的关键控制参数。基于研究结果,建议增加洒水频率、安装防风网并促进镁渣利用,以有效控制粉尘风险。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9059/12031188/953e559f99c3/toxics-13-00307-g001.jpg

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