Farooq Umar, Bertana Valentina, Mossotti Giulia, Ferrero Sergio, Scaltrito Luciano
Chilab-ITEM Laboratory, Department of Applied Science and Technology (DISAT), Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin, Italy.
Department of Science and Technology Innovation (DISIT), Università del Piemonte Orientale, Viale Teresa Michel 11, 15121 Alessandria, Italy.
Polymers (Basel). 2025 Apr 14;17(8):1056. doi: 10.3390/polym17081056.
Nanocomposite laminates containing carbon fibers, epoxy, and multiwalled carbon nanotubes were fabricated using a vacuum bag process. Ecofriendly ionic liquid (5 wt%)-treated multiwalled carbon nanotubes (pristine and nickel-coated) were added to the epoxy independently, in amounts ranging from 1 wt% to 3 wt%, in order to tailor the mechanical, electrical, and thermal performance of manufactured carbon fiber epoxy composite laminates. These nanocomposite laminates were later characterized through flexural testing, dynamic mechanical analysis, impedance spectroscopy, thermal conductivity tests, and FTIR spectroscopy to evaluate their suitability for battery pack applications. The findings showed that both types of multiwalled carbon nanotubes exhibited multifaceted effects on the properties of bulk hybrid carbon fiber epoxy nanocomposite laminates. For instance, the flexural strength of the composites containing 3.0 wt% of ionic liquid-treated pristine multiwalled carbon nanotubes reached 802.8 MPa, the flexural modulus was 88.21 GPa, and the storage modulus was 18.2 GPa, while the loss modulus peaked at 1.76 GPa. The thermal conductivity of the composites ranged from 0.38869 W/(m · K) to 0.69772 W/(m · K), and the electrical resistance decreased significantly with the addition of MWCNTs, reaching a minimum of 29.89 Ω for CFRPIP-1.5 wt%. The structural performance of hybrid nanocomposites containing ionic liquid-treated pristine multiwalled carbon nanotubes was higher than that of the hybrid nanocomposite of ionic liquid-treated Ni-coated multiwalled carbon nanotubes, although the latter was found to possess better functional performance.
采用真空袋工艺制备了含有碳纤维、环氧树脂和多壁碳纳米管的纳米复合层压板。将环保离子液体(5 wt%)处理过的多壁碳纳米管(原始的和镀镍的)分别以1 wt%至3 wt%的量添加到环氧树脂中,以调整所制造的碳纤维环氧树脂复合层压板的机械、电气和热性能。随后通过弯曲测试、动态力学分析、阻抗谱、热导率测试和傅里叶变换红外光谱对这些纳米复合层压板进行表征,以评估它们在电池组应用中的适用性。研究结果表明,两种类型的多壁碳纳米管对本体混合碳纤维环氧树脂纳米复合层压板的性能都表现出多方面的影响。例如,含有3.0 wt%离子液体处理过的原始多壁碳纳米管的复合材料的弯曲强度达到802.8 MPa,弯曲模量为88.21 GPa,储能模量为18.2 GPa,而损耗模量在1.76 GPa时达到峰值。复合材料的热导率范围为0.38869 W/(m·K)至0.69772 W/(m·K),并且随着多壁碳纳米管的添加,电阻显著降低,对于CFRPIP - 1.5 wt%,电阻最小值达到29.89Ω。含有离子液体处理过的原始多壁碳纳米管的混合纳米复合材料的结构性能高于离子液体处理过的镀镍多壁碳纳米管的混合纳米复合材料,尽管发现后者具有更好的功能性能。