Study on the Influence and Mechanism of Steel, Polyvinyl Alcohol, and Polyethylene Fibers on Slag-Yellow River Sediment Geopolymers.

Steel fibers (STs), polyvinyl alcohol fibers (PVAs), and polyethylene fibers (PEs) were selected to systematically investigate the effects of different fiber types and dosages on the workability (slump and spread) and mechanical properties (compressive strength and splitting tensile strength) of slag-Yellow River sand geopolymer eco-cementitious materials. By combining microstructural testing techniques such as thermogravimetric-differential thermal analysis (TG-DTA), X-ray diffraction (XRD), and scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), the influence mechanisms of fibers on the characteristic products and microstructure of the matrix were thoroughly revealed, and the role of fibers in the strength development of Yellow River sediment-based geopolymers was elucidated. The results show that as the fiber content increases, the workability of the mixture significantly decreases. The appropriate incorporation of steel fibers and PVAs can significantly enhance the strength and toughness of the matrix. When the fiber dosage is 1%, the 28-day compressive strength of specimens with steel fibers and PVAs increased by 25.93% and 21.96%, respectively, compared to the control group, while the splitting tensile strength increased by 50.00% and 60.34%, respectively. However, the mechanisms of action differ significantly; steel fibers primarily enhance the compressive performance of the matrix through their high stiffness and strength, whereas PVAs inhibit crack propagation through their flexibility and excellent bonding properties. In contrast, the strength improvement of PEs is mainly reflected in toughening. When the fiber dosage is 1.5%, the 28-day splitting tensile strength of PE specimens increased by 72.61%, and the tensile-to-compressive ratio increased by 92.32% compared to the control group. Microstructural analysis indicates that the incorporation of different types of fibers does not alter the types of characteristic products in alkali-activated cementitious materials, but excessive fiber content affects the generation of gel-like products and the distribution of free water, thereby altering the thermal decomposition behavior of characteristic gel products. Additionally, the matrix incorporating PEs forms a honeycomb-like amorphous gel, resulting in weak interfacial bonding between the fibers and the matrix. This is one of the main reasons for the limited reinforcing effect of PEs at the microscopic scale and a key factor for their inferior long-term performance compared to steel fibers and PVAs. This study provides theoretical foundations and practical guidance for optimizing the performance of fiber-reinforced geopolymer materials.