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通过活化法优化的奥利弗木材活性炭的超级电容器性能

Supercapacitor Performance of Activated Carbon from Oliver Wood Optimized by the Activation Method.

作者信息

Song Haitao, Qu Qiang, Yang Zhuangzhuang, Zhang Yanrong, Qiu Ling, Zhao Yibo, Li Chenguang, Zhu Mingqiang, Yang Xuanmin

机构信息

College of Chemistry & Pharmacy, Northwest A&F University, Yangling, Shaanxi 712100, P. R. China.

College of Mechanical and Electronic Engineering, Northwest A&F University, Yangling, Shaanxi 712100, P. R. China.

出版信息

ACS Omega. 2025 Apr 10;10(15):15368-15380. doi: 10.1021/acsomega.4c11529. eCollection 2025 Apr 22.

Abstract

Amid the growing demand for sustainable energy storage, biomass-derived porous carbons have emerged as eco-friendly alternatives to conventional electrode materials. This study shows that activated carbon prepared by one-step activation exhibits an enhanced specific surface area and pore volume. The optimum parameter for ameliorating the structural and electrochemical properties is 60 min of microwave heating. The specific surface area, pore volume, and mesopore volume of the resulting activated carbon (EUAC1-60) achieve 1589.0 m/g, 0.82 cm/g, and 0.28 cm/g, respectively. EUAC1-60 exhibits an exceptional defect degree with an / value of 0.92 and can provide ample active sites for ion storage. The electrochemical investigation shows that the EUAC1-60 electrode has the highest specific capacitance of 232.92 F/g at a current density of 0.2 A/g. In addition, continuous cycling performance at a current density of 1 A/g validates its exceptional stability with capacitance retention of 89.90% and Coulombic efficiency of 117.21% after 10,000 cycles. The zinc ion hybrid supercapacitor with the EUAC1-60 cathode and Zn foil anode displayed an excellent energy density performance of 95.58 W h/kg at a power density of 64,800 W/kg. This research presents an innovative approach to the fabrication of high-performance activated carbon electrode materials from Oliver, demonstrating its promising potential in supercapacitor applications.

摘要

在对可持续储能需求不断增长的背景下,生物质衍生的多孔碳已成为传统电极材料的环保替代品。本研究表明,一步活化制备的活性炭具有更高的比表面积和孔体积。改善结构和电化学性能的最佳参数是微波加热60分钟。所得活性炭(EUAC1-60)的比表面积、孔体积和中孔体积分别达到1589.0 m²/g、0.82 cm³/g和0.28 cm³/g。EUAC1-60表现出异常的缺陷程度,I⁻/I₃⁻值为0.92,可为离子存储提供充足的活性位点。电化学研究表明,EUAC1-60电极在电流密度为0.2 A/g时具有最高比电容232.92 F/g。此外,在1 A/g电流密度下的连续循环性能验证了其卓越的稳定性,在10000次循环后电容保持率为89.90%,库仑效率为117.21%。以EUAC1-60为正极、锌箔为负极的锌离子混合超级电容器在功率密度为64800 W/kg时表现出95.58 W h/kg的优异能量密度性能。本研究提出了一种从奥利弗制备高性能活性炭电极材料的创新方法,证明了其在超级电容器应用中的广阔前景。

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