Toward Hydrogen Mobility: Challenges and Strategies in Electrocatalyst Durability for Long-Term PEMFC Operation.

Proton exchange membrane fuel cells (PEMFCs) are emerging as a key technology in the transition to hydrogen-based energy systems, particularly for heavy-duty vehicles (HDVs) that face operational challenges, such as frequent startup-shutdown cycles and fuel starvation. However, the widespread adoption of PEMFCs has been limited by their durability and long-term performance issues, which are crucial for heavy-duty applications. This Perspective focuses on recent advancements in PEMFC catalysts and supports, with an emphasis on strategies to enhance their durability. We introduce Pt-based intermetallic catalysts, including Pt transition metal (TM) alloys, which offer improved stability and activity through regular atomic arrangements and strengthened metal-support interactions. Hybrid catalysts combining Pt with M-N-C (M = Fe, Co) have shown promise in boosting performance by enhancing the catalytic activity while reducing the platinum content. Moreover, stringent conditions must be met to meet the HDV requirements. Consequently, alternative support materials, such as metal oxides and graphitized carbons, have been introduced to enhance both the corrosion resistance and the electrical conductivity, thereby addressing the limitations of conventional carbon supports. Structural innovations and material advancements are essential for optimizing catalysts and supports to achieve long-term PEMFC performance. This Perspective provides a comprehensive overview of key developments in catalyst and support design, offering insights into current challenges and future directions for achieving durable and cost-effective PEMFCs.