用于聚集诱导发光（AIE）和聚集导致猝灭（ACQ）性质转换的阳离子氮杂三亚苯衍生物的正交合成
Orthogonal Synthesis of Cationic Azatriphenylene Derivatives for Aggregation-Induced Emission (AIE) and Aggregation-Caused Quenching (ACQ) Property Switching.
作者信息
Ohno Yushi, Ehara Tsukasa, Sato Kosuke, Hifumi Ryoyu, Tomita Ikuyoshi, Inagi Shinsuke
机构信息
Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Institute of Science Tokyo, 4259 Nagatsuta-cho, Midori-ku, Yokohama, Kanagawa 226-8501, Japan.
出版信息
Org Lett. 2025 May 16;27(19):4964-4968. doi: 10.1021/acs.orglett.5c01277. Epub 2025 May 4.
Herein, we report a divergent synthesis of cationic azatriphenylene derivatives using orthogonal control of thermal and electro-oxidative pyridination, which transforms the single precursor into controlled products with perfect selectivity. Simultaneously, two switchable reactions afford the corresponding pyridinium salts with different optical properties such as aggregation-induced emission (AIE) and aggregation-caused quenching (ACQ) effects.
在此，我们报道了一种阳离子氮杂三亚苯衍生物的发散合成方法，该方法利用热吡啶化和电氧化吡啶化的正交控制，将单一前体以完美的选择性转化为可控产物。同时，两个可切换的反应可得到具有不同光学性质的相应吡啶鎓盐，如聚集诱导发光（AIE）和聚集导致猝灭（ACQ）效应。
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