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一种基于纺织品的高灵敏度和防水摩擦纳米发电机的简便策略。

A Facile Strategy for Textile-Based Highly Sensitive and Water-Resistant Triboelectric Nanogenerator.

作者信息

Shi Anqi, Luo Bin, Liu Wendi, Chen Wenjing, Li Zhen, Wang Shilong, Jiang Ligang, Zhang Hongnan, Qin Xiaohong, Sun Wei

机构信息

State Key Laboratory for Advanced Fiber Materials, Institute of Functional Materials, College of Materials Science and Engineering, Donghua University, Shanghai, 201620, P. R. China.

Key Laboratory of Textile Science & Technology, Ministry of Education, College of Textiles, Donghua University, Shanghai, 201620, P. R. China.

出版信息

Adv Mater. 2025 Jul;37(28):e2420459. doi: 10.1002/adma.202420459. Epub 2025 May 7.

Abstract

The demand for real-time physiological monitoring drives innovation in triboelectric nanogenerators (TENGs). TENGs offer promise for real-time dynamic monitoring, but they are often complicated to manufacture, have low sensitivity, and are easily disturbed by ambient humidity. Herein, a fabric-based integrated triboelectric nanogenerator (F-TENG) is developed, employing waterborne polyurethane (WPU) as both a water-resistant encapsulation and friction layer, and polypyrrole (PPy) as a friction and conductive layer. This design simplifies the fabrication process while simultaneously improving the device's resistance to environmental factors. The micro-filament structure enables localized contact-separation during deformation, initiating the triboelectric effect, while the 3D architecture amplifies local strain, further enhancing sensitivity to weak signals. F-TENG demonstrates effective voltage output during carotid and respiratory monitoring, highlighting its capability to detect subtle physiological signals. Furthermore, F-TENG maintains stable performance under humid conditions, retaining 78.78% of its output voltage as relative humidity increased from 20% to 80%. When implants in the moist environment of a rat's leg, F-TENG exhibits a notable output of 21 V. In addition, the inherent antibacterial properties of F-TENG further enhance its application potential. These findings position F-TENG as a robust and versatile platform for dynamic monitoring, wearable electronics, and integrated diagnostic and therapeutic systems.

摘要

对实时生理监测的需求推动了摩擦纳米发电机(TENGs)的创新。TENGs为实时动态监测带来了希望,但它们通常制造复杂,灵敏度低,并且容易受到环境湿度的干扰。在此,开发了一种基于织物的集成摩擦纳米发电机(F-TENG),采用水性聚氨酯(WPU)作为防水封装层和摩擦层,聚吡咯(PPy)作为摩擦和导电层。这种设计简化了制造过程,同时提高了器件对环境因素的抵抗力。微丝结构在变形过程中实现局部接触-分离,引发摩擦电效应,而三维结构放大局部应变,进一步提高对微弱信号的灵敏度。F-TENG在颈动脉和呼吸监测过程中展示了有效的电压输出,突出了其检测细微生理信号的能力。此外,F-TENG在潮湿条件下保持稳定性能,当相对湿度从20%增加到80%时,其输出电压保留了78.78%。当植入大鼠腿部的潮湿环境中时,F-TENG表现出21 V的显著输出。此外,F-TENG固有的抗菌特性进一步提高了其应用潜力。这些发现使F-TENG成为一个用于动态监测、可穿戴电子设备以及集成诊断和治疗系统的强大且通用的平台。

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