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极端塑性变形导致的各种应力状态引起的CuO氧化物破碎

Fragmentation of CuO Oxides Caused by Various States of Stress Resulting from Extreme Plastic Deformation.

作者信息

Zasadzińska Małgorzata

机构信息

Faculty of Non-Ferrous Metals, AGH University of Krakow, al. Mickiewicza 30, 30-059 Krakow, Poland.

出版信息

Materials (Basel). 2025 Apr 10;18(8):1736. doi: 10.3390/ma18081736.

Abstract

The development of microelectronics results in higher demand for copper microwires and thin foils. Higher demand requires conducting research to obtain knowledge on the influence of extreme plastic deformation on materials' susceptibility to plastic processing without the loss of coherence. One of the key factors contributing to rupture during the plastic deformation of copper is the presence of micrometer-sized, eutectic CuO oxides, which are weakly bound to the copper matrix. These oxides are formed during the metallurgical stage of wire rod copper manufacturing. Copper wire rod of the ETP (electrolytic tough pitch) grade was subjected to wire drawing followed by cold-rolling. Applying different states of stress during plastic deformation (wire drawing, cold-rolling, and upsetting) made it possible to specify the conditions required for CuO oxides' fragmentation due to the extreme total deformation. Qualitative and quantitative analyses of the CuO oxides' evolution and fragmentation as the plastic deformation progressed were the main focus of this paper. It was determined that major fragmentation occurred during the initial stages of plastic deformation. Applying further extreme deformation or changing the state of stress during plastic deformation did not facilitate the continuation of fragmentation. It was only their shape that was becoming elongated.

摘要

微电子学的发展导致对铜微丝和薄箔的需求增加。更高的需求需要开展研究,以获取关于极端塑性变形对材料塑性加工敏感性的影响的知识,同时不丧失连贯性。导致铜塑性变形过程中破裂的关键因素之一是存在微米级的共晶CuO氧化物,这些氧化物与铜基体的结合较弱。这些氧化物是在盘条铜制造的冶金阶段形成的。对ETP(电解韧铜)级的铜盘条进行拉丝,然后冷轧。在塑性变形(拉丝、冷轧和镦粗)过程中施加不同的应力状态,使得确定由于极端总变形导致CuO氧化物破碎所需的条件成为可能。随着塑性变形的进行,对CuO氧化物的演变和破碎进行定性和定量分析是本文的主要重点。已确定主要破碎发生在塑性变形的初始阶段。在塑性变形过程中施加进一步的极端变形或改变应力状态并不能促进破碎的继续进行。只是它们的形状变得拉长了。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4a21/12028670/7fc11042be52/materials-18-01736-g001.jpg

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