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不同类别轻质油在部分反应性橡胶粉改性沥青中的有效性

Effectiveness of Different Categories of Light Oils in Partially Reactive Crumb Rubber-Modified Asphalt.

作者信息

Wen Dean, Ge Dongdong, Wang Yantao, Lv Songtao, Liu Qian, Liu Shuxian

机构信息

CCCC-SHB Fourth Engineering Co., Ltd., Luoyang 471013, China.

National Key Laboratory of Green and Long-Life Road Engineering in Extreme Environment, Changsha University of Science & Technology, Changsha 410114, China.

出版信息

Materials (Basel). 2025 Apr 19;18(8):1871. doi: 10.3390/ma18081871.

Abstract

Rubber-modified asphalt (RMA) faces several challenges, including poor workability, difficult construction, and high energy consumption. The incorporation of renewable light oils offers a promising solution to address issues such as high viscosity and elevated carbon emissions in asphalt modified with a high dosage of rubber powder. The investigation of light oil and rubber powder composite-modified asphalt under low-temperature (160 °C) and short-term (30 min) shear processes is essential for understanding its rheological behavior and modification mechanism. This study explores composite-modified asphalt prepared with four types of light oils (fatty acids, aromatic oil, tall oil, and paraffin oil) at dosages of 10% and 15%, combined with 20% rubber powder. Conventional penetration and viscosity tests were carried out to assess the overall physical properties of the composite-modified asphalts, while rheological tests were conducted to examine their performance at high temperatures. Fourier transform infrared spectroscopy (FTIR) and fluorescence microscopy (FM) were employed to explore the interaction mechanisms that occurred between the light oils, rubber powder, and asphalt. The results suggest that the addition of various light oils leads to a reduction in the viscosity of rubber-modified asphalt, with the extent of reduction varying across different oils. Notably, 10% tall oil demonstrates the most significant reduction in viscosity while also facilitating the dissolution of rubber powder. The high-temperature PG-grade rubberized asphalt improved with the incorporation of light oils, with 5% tall oil yielding the highest PG grade of PG 82-34. FTIR analysis confirmed that light oils and rubber were physically blended in the asphalt, with the light components of the oils being absorbed by the asphalt. FM observations revealed that light oils promote the swelling of rubber particles, with the rubber particles fully swelling in tall oil. Considering the reduction in viscosity, the performance at both high and low temperatures, elasticity, and the extent of rubber particle swelling, tall oil is identified as the most effective material for preparing light oil-rubber composite-modified asphalt using the low-temperature, short-term shear process.

摘要

橡胶改性沥青(RMA)面临着诸多挑战,包括施工性能差、施工困难以及能源消耗高。掺入可再生轻质油为解决高剂量橡胶粉改性沥青中高粘度和高碳排放等问题提供了一种有前景的解决方案。研究低温(160℃)和短期(30分钟)剪切过程下轻质油与橡胶粉复合改性沥青对于理解其流变行为和改性机理至关重要。本研究探索了用四种轻质油(脂肪酸、芳烃油、妥尔油和石蜡油)以10%和15%的剂量与20%橡胶粉制备的复合改性沥青。进行了常规针入度和粘度试验以评估复合改性沥青的整体物理性能,同时进行了流变试验以检测其高温性能。采用傅里叶变换红外光谱(FTIR)和荧光显微镜(FM)来探究轻质油、橡胶粉和沥青之间发生的相互作用机理。结果表明,添加各种轻质油会导致橡胶改性沥青的粘度降低,不同油品的降低程度各不相同。值得注意的是,10%的妥尔油粘度降低最为显著,同时还促进了橡胶粉的溶解。掺入轻质油后高温PG级橡胶化沥青得到改善,5%的妥尔油产生了最高的PG等级PG 82 - 34。FTIR分析证实轻质油和橡胶在沥青中物理混合,油中的轻质成分被沥青吸收。FM观察表明轻质油促进橡胶颗粒的溶胀,橡胶颗粒在妥尔油中完全溶胀。考虑到粘度降低、高低温性能、弹性以及橡胶颗粒溶胀程度,妥尔油被确定为使用低温、短期剪切工艺制备轻质油 - 橡胶复合改性沥青最有效的材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6ab1/12029097/0970680ff6d0/materials-18-01871-g001.jpg

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