Elzwawy Amir, Morsy Mohamed, Zain Sara, Abdel-Salam Ahmed I
Ceramics Department, Advanced Materials Technology and Mineral Resources Research Institute, National Research Centre (NRC) 33 El Bohouth St., Dokki Giza 12622 Egypt
Nanotechnology Research Centre (NTRC), The British University in Egypt (BUE) Suez Desert Road, El-Sherouk City Cairo 11837 Egypt.
RSC Adv. 2025 May 7;15(19):14797-14808. doi: 10.1039/d5ra01883h. eCollection 2025 May 6.
Determination of the relative humidity in the surrounding environment is essential for numerous industrial and technological applications. In this work, we successfully prepared CuO-rGO doped with varied Ag concentrations (0-1.5 wt%). The XRD measurements demonstrated that the structures were successfully developed with an average crystallite size of 30-40 nm as reflected from the (111) plane, with a dominating cubic phase. The SEM morphological characteristics demonstrated that the cubic structure was Cu-based, whilst the sheet-like structure was attributable to 2D rGO. The cubic structure tended to lose its regular shape, while the size tended to be reduced as the Ag doping ratio increased. Elemental analysis was confirmed through EDX for CuO-rGO doped with 1.5 wt% Ag, reflecting 35, 13, 1.4, and 50.6 wt% of C, O, Ag, and Cu, respectively. Assessment of the antimicrobial assets of the nanostructures G (), and G bacteria () presented the highest activity for CuO-rGO doped with 1 wt% Ag. The humidity sensing evaluations were revealed throughout a wide set of frequencies (50-10 kHz) and humidity levels (11-97% RH). The optimum frequency was optimized as 50 Hz. The acquired response and recovery times were 154, and 172 s, respectively, while the sensitivity was 2 × 10 Ω per RH for CuO-rGO doped with 1.0 wt% Ag. Remarkably, the recovery time for CuO-rGO doped with 1.5 wt% Ag was 17 s. The sensor demonstrate decent repeatability for four cycles between 11% and 75% RH at a testing frequency of 50 Hz. The results nominate this structure as an affordable, low-cost, and applicable humidity sensor valid for nanotechnological and materials science routes.
测定周围环境中的相对湿度对于众多工业和技术应用至关重要。在这项工作中,我们成功制备了掺杂不同银浓度(0 - 1.5 wt%)的CuO - rGO。XRD测量表明,从(111)面反映出结构成功形成,平均晶粒尺寸为30 - 40 nm,以立方相为主。SEM形态特征表明立方结构是以铜为基的,而片状结构归因于二维rGO。随着银掺杂比例增加,立方结构倾向于失去其规则形状,尺寸也趋于减小。通过EDX对掺杂1.5 wt%银的CuO - rGO进行元素分析得到证实,分别反映出C、O、Ag和Cu的含量为35%、13%、1.4%和50.6%。对纳米结构对G()和G细菌()的抗菌性能评估表明,掺杂1 wt%银的CuO - rGO具有最高活性。在很宽的频率范围(50 - 10 kHz)和湿度水平(11 - 97% RH)内进行了湿度传感评估。最佳频率优化为50 Hz。对于掺杂1.0 wt%银的CuO - rGO,获得的响应时间和恢复时间分别为154 s和174 s,灵敏度为每RH 2×10Ω。值得注意的是,掺杂1.5 wt%银的CuO - rGO的恢复时间为17 s。该传感器在50 Hz测试频率下,在11%至75% RH之间的四个循环中表现出良好的重复性。结果表明这种结构是一种经济实惠、低成本且适用于纳米技术和材料科学领域的湿度传感器。