Kurumaji Takashi, Facio Jorge I, Mitsuishi Natsuki, Imajo Shusaku, Gen Masaki, Kimata Motoi, Ye Linda, Graf David, Sakano Masato, Kitamura Miho, Yamagami Kohei, Ishizaka Kyoko, Kindo Koichi, Arima Taka-Hisa
Division of Physics, Mathematics and Astronomy, California Institute of Technology, Pasadena, CA, 91125, USA.
Department of Advanced Materials Science, University of Tokyo, Kashiwa, 277-8561, Japan.
Adv Sci (Weinh). 2025 Jul;12(27):e2501669. doi: 10.1002/advs.202501669. Epub 2025 May 8.
Nodal-line semimetals are a class of topological materials hosting one dimensional lines of band degeneracy. Kramers nodal-line (KNL) metals/semimetals have recently been theoretically recognized as a class of topological states inherent to all non-centrosymmetric achiral crystal lattices. The electronic structure of candidate KNL semimetal YAuGe is investigated by angle-resolved photoemission spectroscopy (ARPES) and quantum oscillations as well as by density functional theory (DFT) calculations. DFT has revealed that YAuGe hosts KNLs on the Γ-A-L-M plane of the Brillouin zone, that are protected by the time reversal and mirror-inversion symmetries. Through ARPES and quantum oscillations, signatures of hole bands enclosing the Γ point are identified, and the observed splitting of quantum oscillation frequency with angle is attributed to spin-orbit-coupling-induced band splitting away from the KNLs. Furthermore, it is shown that the degeneracy of the nodal lines along the Γ-A line is lifted by the time-reversal-symmetry breaking when the Y is substituted by magnetic R ions (R = rare earth). This becomes a source of Berry curvature and contributes to the anomalous Hall effect in magnetic RAuGe. These findings establish RAuGe as a new class of KNL semimetals offering significant potential for engineering of anomalous magnetotransport properties via magnetic rare-earth substitution.
节线半金属是一类具有一维能带简并线的拓扑材料。克莱默斯节线(KNL)金属/半金属最近在理论上被认为是所有非中心对称非手性晶格所固有的一类拓扑态。通过角分辨光电子能谱(ARPES)、量子振荡以及密度泛函理论(DFT)计算,对候选的KNL半金属YAuGe的电子结构进行了研究。DFT表明,YAuGe在布里渊区的Γ - A - L - M平面上存在节线,这些节线受到时间反演和镜面对称性的保护。通过ARPES和量子振荡,识别出了围绕Γ点的空穴带的特征,并且观察到的量子振荡频率随角度的分裂归因于自旋轨道耦合引起的能带从节线处分裂。此外,研究表明,当Y被磁性R离子(R = 稀土)取代时,沿Γ - A线的节线简并会因时间反演对称性破缺而解除。这成为贝里曲率的一个来源,并对磁性RAuGe中的反常霍尔效应有贡献。这些发现确立了RAuGe作为一类新的KNL半金属,通过磁性稀土取代为反常磁输运性质的工程设计提供了巨大潜力。