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家用洗衣机去除衣物上铅的效果:一项试点研究。

Residential washing machine efficacy in removing lead from clothing: A pilot study.

作者信息

Achutan Chandran, Carlson Krystin, LeVanseler Kerri, Couch James

机构信息

Division of Science Integration, National Institute for Occupational Safety and Health, Cincinnati, Ohio.

Synergy America, Inc, Duluth, Georgia.

出版信息

J Occup Environ Hyg. 2025 May 12:1-9. doi: 10.1080/15459624.2025.2497871.

Abstract

Workers exposed to lead sometimes wear their work clothes home. It is possible that lead from contaminated work clothing can transfer to uncontaminated clothing, including children's items that may be in the same load, during laundering. This is concerning because lead is especially toxic for children. The purpose of this pilot study was to understand lead extraction from fabrics typically worn by workers, the amount of lead removed during normal laundering, and lead transfer to other fabrics during a laundry washing cycle. The study validated EPA analytical method 200.8 Determination of Trace Elements in Waters and Wastes by Inductively Coupled Plasma-Mass Spectrometry to analyze lead in Dickies pant fabric (DPF), T-shirt material (TSM), and blue jeans material (BJM). Because this methodology of extracting lead from fabrics is novel, a priori definitions of accuracy and precision used were ± 40%. Researchers spiked two levels (9 µg and 9,000 µg) of lead nitrate and three levels (9 µg, 900 µg, and 9,000 µg) of lead carbonate on 9 cm fabric swatches and extracted lead by microwave-assisted digestion. Across all spike levels, mean recoveries were within 60% and 140% recovery. All percent coefficient of variation values were less than 20% for lead nitrate, indicating that this method for lead nitrate was sufficiently accurate and precise. For lead carbonate, the method was neither accurate nor precise at the 9 and 900 µg levels but was sufficiently accurate and precise at the 9,000 µg level. Eighteen loads of fabric swatches were spiked with either lead form and laundered in a washing machine using a common laundry detergent. The mean amount of lead removed from laundered DPF and TSM was similar (97.4 and 95.9%) and significantly higher ( < 0.05) compared to laundered BJM (70.6%). The amount of lead carbonate removed (92.6%) was significantly higher ( < 0.05) than lead nitrate (83.4%). The levels of lead that transferred from spiked fabric to bedsheets included in the same washing load were less than 0.5 µg. It is important to follow public health recommendations, such as laundering work clothes separately.

摘要

接触铅的工人有时会穿着工作服回家。在洗涤过程中,受污染工作服上的铅有可能转移到未受污染的衣物上,包括可能在同一批次中的儿童衣物。这令人担忧,因为铅对儿童尤其具有毒性。这项初步研究的目的是了解从工人通常穿着的织物中提取铅的情况、正常洗涤过程中去除的铅量以及在洗衣周期中铅向其他织物的转移情况。该研究验证了美国环境保护局(EPA)的分析方法200.8《通过电感耦合等离子体质谱法测定水和废物中的微量元素》,以分析迪凯斯工装裤面料(DPF)、T恤面料(TSM)和蓝色牛仔裤面料(BJM)中的铅。由于这种从织物中提取铅的方法是新颖的,所使用的准确度和精密度的先验定义为±40%。研究人员在9厘米的织物样本上添加了两个水平(9微克和9000微克)的硝酸铅和三个水平(9微克、900微克和9000微克)的碳酸铅,并通过微波辅助消解提取铅。在所有添加水平下,平均回收率在60%至140%之间。硝酸铅的所有变异系数百分比值均小于20%,表明该硝酸铅方法具有足够的准确度和精密度。对于碳酸铅,该方法在9微克和900微克水平时既不准确也不精密,但在9000微克水平时具有足够的准确度和精密度。18批织物样本添加了其中一种铅形态,并使用普通洗衣粉在洗衣机中洗涤。洗涤后的DPF和TSM去除的铅平均量相似(分别为97.4%和95.9%),与洗涤后的BJM(70.6%)相比显著更高(P<0.05)。去除的碳酸铅量(92.6%)显著高于硝酸铅(83.4%)。在同一洗涤批次中,从添加铅的织物转移到床单上的铅含量低于0.5微克。遵循公共卫生建议很重要,比如将工作服分开洗涤。

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