Lv Guanglei, Xiao Peng, Su Yuhua, Liu Xinmei
College of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao 266580, China.
State Key Laboratory for Heavy Oil Processing, China University of Petroleum (East China), Qingdao 266580, China.
Materials (Basel). 2025 Apr 24;18(9):1920. doi: 10.3390/ma18091920.
Epoxy resin (EP) is a candidate material for offshore oil platform safety signs due to its excellent corrosion resistance property. However, fabricating EP with good anti-corrosion as well as mechanical properties remains a significant challenge. Here, we report a new modification strategy to simultaneously improve the corrosion resistance and mechanical performance of EP by coupling it with KH550 silanized graphene oxide (KGO) and KH550 silanized glass fiber (KGF). KGO and KGF were grafted onto EP to obtain the modified EP material, i.e., KGO/KGF/EP composites and were characterized by FITR, XRD, SEM, and TGA to confirm the successful synthesis of the composites. It is shown that the tensile strength and adhesion strength of KGO/KGF/EP were 85.5 MPa and 16.0 MPa, which are 10.3% and 23.1% higher than KGO/GF/EP. Compared with KGF/EP, the corrosion potential increased by 9.9% and the corrosion rate decreased by 98.8%. Moreover, fluid-structure coupling simulation indicated the maximum stress of the material was within the criteria under extreme wind speeds, demonstrating its great potential for offshore oil platform safety sign applications.
环氧树脂(EP)因其优异的耐腐蚀性能,是海上石油平台安全标志的候选材料。然而,制备具有良好耐腐蚀性能和机械性能的EP仍然是一项重大挑战。在此,我们报告一种新的改性策略,通过将EP与KH550硅烷化氧化石墨烯(KGO)和KH550硅烷化玻璃纤维(KGF)偶联,同时提高EP的耐腐蚀性能和机械性能。将KGO和KGF接枝到EP上以获得改性EP材料,即KGO/KGF/EP复合材料,并通过傅里叶变换红外光谱(FITR)、X射线衍射(XRD)、扫描电子显微镜(SEM)和热重分析(TGA)对其进行表征,以确认复合材料的成功合成。结果表明,KGO/KGF/EP的拉伸强度和粘结强度分别为85.5 MPa和16.0 MPa,比KGO/GF/EP分别高出10.3%和23.1%。与KGF/EP相比,腐蚀电位提高了9.9%,腐蚀速率降低了98.8%。此外,流固耦合模拟表明,在极端风速下,材料的最大应力在标准范围内,这表明其在海上石油平台安全标志应用方面具有巨大潜力。