Šmit Žiga, Milavec Tina
Faculty of Mathematics and Physics, University of Ljubljana, Jadranska 19, SI-1000 Ljubljana, Slovenia.
Jožef Stefan Institute, Jamova 39, SI-1000 Ljubljana, Slovenia.
Materials (Basel). 2025 May 6;18(9):2135. doi: 10.3390/ma18092135.
A series ( = 22) of glasses from the site Kapucinski vrt (garden of the Capuchin monastery, 5th-17th c. CE) in Koper (Capodistria), a port town in the northern Adriatic, was measured using a combined PIXE and PIGE method. Koper has been continuously populated since the late Roman period, with a rich medieval history, thus offering an opportunity to study Early Medieval glass. Stemmed goblet fragments, in the original publication dated between the 6th-9th centuries CE, and several other vessel types (beakers and flasks or bottles and lamps) were selected for analysis. The measurements were expected to show the trends in glass production and consumption from Late Antiquity until the Middle Ages, notably the transition between natron to plant ash glass and the supply of fresh glass. Among the set of 22 glass vessel fragments, both natron and plant ash glass were identified. For finer classification, we relied on a newly developed method of Euclidean distances with respect to major concentrations. Natron glass of the types Foy 2.1 (9 examples), Magby (2 examples), and Levantine I (Apollonia; 2 examples) was found. Two glasses remain undetermined but testify to an Egyptian origin. Most natron glasses show signs of recycling. Among the three unrecycled glasses (about 20% of the whole set), there are two examples of Levantine glass and a Magby glass lamp; this may indicate a modest supply of fresh glass during the period. Plant ash glass may be attributed to the Early or High Middle Ages, exploiting the purified alkalis of the Levantine coasts (known as in later Venetian glassmaking), and the admixture of impurities in the siliceous sands suggests the circulation and consumption of glass that was produced and traded in the eastern Mediterranean since the 10th century CE.
对来自科佩尔(卡波迪斯特里亚)港口城市亚得里亚海北部的卡普钦斯基·弗尔特遗址(卡普钦修道院花园,公元5至17世纪)的一系列(=22件)玻璃制品,采用质子激发X射线发射(PIXE)和质子诱发γ射线发射(PIGE)联合方法进行了测量。自罗马晚期以来,科佩尔一直有人居住,拥有丰富的中世纪历史,因此为研究早期中世纪玻璃提供了契机。挑选了高脚杯碎片(在最初的出版物中年代为公元6至9世纪)以及其他几种容器类型(烧杯、烧瓶或瓶子、灯具)进行分析。这些测量旨在展示从古代晚期到中世纪玻璃生产和消费的趋势,特别是从天然碱玻璃到草木灰玻璃的转变以及新鲜玻璃的供应情况。在这22件玻璃容器碎片中,既鉴定出了天然碱玻璃,也鉴定出了草木灰玻璃。为了进行更精细的分类,我们依靠一种新开发的基于主要成分浓度的欧几里得距离方法。发现了Foy 2.1型(9件)、马格比型(2件)和黎凡特I型(阿波利纳里斯;2件)的天然碱玻璃。有两件玻璃制品尚未确定,但证明来自埃及。大多数天然碱玻璃有回收利用的迹象。在三件未回收的玻璃制品中(约占总数的20%),有两件黎凡特玻璃制品和一件马格比玻璃灯具;这可能表明在该时期新鲜玻璃的供应较为有限。草木灰玻璃可能属于中世纪早期或盛期,利用了黎凡特海岸提纯的碱(在后来的威尼斯玻璃制造中称为 ),硅质砂中杂质的混合表明自公元10世纪以来在地中海东部生产和交易的玻璃的流通和消费情况。