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褐藻中的倍半萜类化合物。

Sesquiterpenes from Brown Algae.

作者信息

Moreno-Gutiérrez Irene, Berenguel-Gómez Sonia, Muñoz-Dorado Manuel, Álvarez-Corral Míriam, Rodríguez-García Ignacio

机构信息

Organic Chemistry, CeiA3, CIAIMBITAL, University of Almeria, 04120 Almería, Spain.

出版信息

Mar Drugs. 2025 May 15;23(5):210. doi: 10.3390/md23050210.

DOI:10.3390/md23050210
PMID:40422800
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12113178/
Abstract

Algae are the group that has managed to generate the largest number of compounds and secondary metabolites with different properties, many of them only present in the aquatic kingdom. Among them, brown algae are one of the main producers within marine ecosystems. Furthermore, one of the main groups of secondary metabolites studied are sesquiterpenes due to the great variety of properties observed, largely due to the great structural variability of these compounds. Many studies have been carried out to isolate and characterize compounds with a sesquiterpene structure from different species of brown algae. This article reviews the natural occurrence of sesquiterpene and derivatives in brown algae. A total of 51 sesquiterpenes isolated from brown algae, having monocyclic, bicyclic, or tricyclic skeletons, as well as 23 sesquiterpenoids with various chemical structures, are depicted. Moreover, there are at least eleven publications focused on the study of the profiles on volatile organic compounds (VOCs) within brown algae, derived using several analytic and extraction techniques, and in the finding of a large variety of structures of sesquiterpenes.

摘要

藻类是能够产生数量最多、具有不同特性的化合物和次生代谢产物的类群，其中许多仅存在于水生生物界。其中，褐藻是海洋生态系统中的主要生产者之一。此外，由于观察到的特性种类繁多，主要是由于这些化合物具有极大的结构变异性，倍半萜是研究的主要次生代谢产物类群之一。已经开展了许多研究，从不同种类的褐藻中分离和鉴定具有倍半萜结构的化合物。本文综述了褐藻中倍半萜及其衍生物的天然存在情况。描绘了从褐藻中分离出的总共51种具有单环、双环或三环骨架的倍半萜，以及23种具有各种化学结构的倍半萜类化合物。此外，至少有11篇出版物专注于研究褐藻中的挥发性有机化合物（VOCs）概况，这些研究采用了多种分析和提取技术，并发现了多种倍半萜结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/8fe6c18dd55d/marinedrugs-23-00210-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/2cabe831afcd/marinedrugs-23-00210-g001.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/c32a7754a239/marinedrugs-23-00210-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/fb83c82d1e77/marinedrugs-23-00210-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/176b7dc129d9/marinedrugs-23-00210-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/caf3a4dc2717/marinedrugs-23-00210-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/6b9720bcf17f/marinedrugs-23-00210-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/90abb4dabedd/marinedrugs-23-00210-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/e9c205af432e/marinedrugs-23-00210-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/edb91ade474d/marinedrugs-23-00210-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/c2363a7ca3a1/marinedrugs-23-00210-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/544b2fd55b1d/marinedrugs-23-00210-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/7a404596512d/marinedrugs-23-00210-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/99c2f6ff3202/marinedrugs-23-00210-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/36f5d62ef9ad/marinedrugs-23-00210-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/34d8c2965da3/marinedrugs-23-00210-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/8fe6c18dd55d/marinedrugs-23-00210-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/2cabe831afcd/marinedrugs-23-00210-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/306a06613ca8/marinedrugs-23-00210-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/f1454e5e4aae/marinedrugs-23-00210-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/c8fea36c2dd6/marinedrugs-23-00210-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/c32a7754a239/marinedrugs-23-00210-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/fb83c82d1e77/marinedrugs-23-00210-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/176b7dc129d9/marinedrugs-23-00210-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/caf3a4dc2717/marinedrugs-23-00210-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/6b9720bcf17f/marinedrugs-23-00210-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/90abb4dabedd/marinedrugs-23-00210-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/e9c205af432e/marinedrugs-23-00210-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/edb91ade474d/marinedrugs-23-00210-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/c2363a7ca3a1/marinedrugs-23-00210-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/544b2fd55b1d/marinedrugs-23-00210-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/7a404596512d/marinedrugs-23-00210-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/99c2f6ff3202/marinedrugs-23-00210-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/36f5d62ef9ad/marinedrugs-23-00210-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/34d8c2965da3/marinedrugs-23-00210-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0807/12113178/8fe6c18dd55d/marinedrugs-23-00210-g019.jpg

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Molecules. 2022 Aug 5;27(15):4997. doi: 10.3390/molecules27154997.
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Seasonal Variability of Volatilome from .从. 中挥发物组的季节性变化。
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Amyloid-β induced neuropathological actions are suppressed by Padina gymnospora (Phaeophyceae) and its active constituent α-bisabolol in Neuro2a cells and transgenic Caenorhabditis elegans Alzheimer's model.节旋藻（Phaeophyceae）及其活性成分α- 倍半水芹醇抑制淀粉样β诱导的神经病理学作用在 Neuro2a 细胞和转基因秀丽隐杆线虫阿尔茨海默病模型中的作用。
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