Electrostatic Field Modification Enhances the Electrocatalytic Oxygen Evolution Reaction Stability of CoFeO Catalysts.

Enhancing the stability of oxygen evolution reaction (OER) catalysts is a critical challenge for realizing efficient water splitting. In this work, we introduce an innovative approach by applying an electric field during the annealing of a CoFeO/C catalyst. By controlling the electric field strength (100 mV) and treatment duration (1 h), we achieved dual optimization of the catalyst's microstructure and electronic environment, resulting in a significant improvement in catalytic stability. The experimental results demonstrate that the electric field-treated catalyst exhibits a reduced overpotential decay (only 0.8 mV) and enhanced stability (retaining 89.1% of its initial activity after 24 h) during extended OER testing. This performance significantly surpasses that of the untreated sample, which showed an overpotential decay of 1.5 mV and retained only 72.5% of its activity after 24 h. X-ray photoelectron spectroscopy (XPS) analysis confirmed that the electric field treatment promoted the formation of oxygen vacancies, substantially improved electron transfer efficiency, and optimized the local electronic environment of Co/Co and Fe/Fe, leading to a decrease in charge transfer resistance (Rct) from 58.2 Ω to 42.9 Ω. This study not only presents a novel strategy for modulating catalyst stability via electric fields but also broadens the design concepts for OER catalytic materials by establishing a structure-activity relationship between electric field strength, microstructure, and catalytic performance, ultimately providing a theoretical foundation and experimental guidance for the development of highly efficient and stable water splitting catalysts.