• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

超晶格储氢合金的研究进展：制备方法、相结构调控及储氢性能

Advances in Superlattice Hydrogen Storage Alloys: Preparation Method, Phase Structure Modulation, and Hydrogen Storage Performance.

作者信息

Zhang Yuqing, Zhang Yajie, He Tianmeng, Wang Hao, Zhang Shubin, Wang Jinpeng, Xue Xiaoyi, Liu Yanrong, Chen Biaohua

机构信息

College of Environmental Science and Engineering, Beijing University of Technology, Beijing 100124, China.

CAS Key Laboratory of Green Process and Engineering, State Key Laboratory of Mesoscience and Engineering, Beijing Key Laboratory of Solid State Battery and Energy Storage Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China.

出版信息

Molecules. 2025 May 14;30(10):2161. doi: 10.3390/molecules30102161.

DOI:10.3390/molecules30102161
PMID:40430333
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12113889/
Abstract

Superlattice hydrogen storage alloys have attracted much attention due to their high capacity, excellent cyclic stability, and moderate operating conditions. This review, focusing on journal articles published between 2020 and 2025, comprehensively covers the impacts of doping with different rare-earth elements and the substitution of different elements on superlattice hydrogen storage alloys and details the influence mechanisms of different preparation methods, such as arc melting and powder metallurgy, on the phase structure of alloys. A thorough analysis is conducted on how rare-earth element doping alters the crystal structure, lattice parameters, and phase stability of alloys, thereby affecting their hydrogen storage performance. Meanwhile, the differences in the effects of different substituting elements at various substitution sites on the phase structure and hydrogen storage performance of alloys are explored, and the regular patterns and influencing factors are summarized. This review provides a new perspective for the design and development of high-performance superlattice hydrogen storage alloys and is expected to contribute to the long-term and sustainable development of clean hydrogen energy.

摘要

超晶格储氢合金因其高容量、优异的循环稳定性和适中的工作条件而备受关注。本综述聚焦于2020年至2025年间发表的期刊文章，全面涵盖了不同稀土元素掺杂以及不同元素替代对超晶格储氢合金的影响，并详细阐述了电弧熔炼和粉末冶金等不同制备方法对合金相结构的影响机制。深入分析了稀土元素掺杂如何改变合金的晶体结构、晶格参数和相稳定性，从而影响其储氢性能。同时，探讨了不同替代元素在不同替代位点对合金相结构和储氢性能影响的差异，并总结了规律模式和影响因素。本综述为高性能超晶格储氢合金的设计与开发提供了新的视角，有望为清洁氢能的长期可持续发展做出贡献。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/e82f8d2d7725/molecules-30-02161-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/642781d9a9b7/molecules-30-02161-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/48a2777637b7/molecules-30-02161-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/f9cac045f49a/molecules-30-02161-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/4aa02b6f6c52/molecules-30-02161-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/e83eac782fc6/molecules-30-02161-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/042bba3e1de0/molecules-30-02161-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/b7f87adc1f91/molecules-30-02161-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/724142027c6b/molecules-30-02161-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/f0cb3d69a63e/molecules-30-02161-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/6137d4d47599/molecules-30-02161-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/effcbb64d859/molecules-30-02161-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/26177c68f58d/molecules-30-02161-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/8bbf08a0180b/molecules-30-02161-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/f9e6c42fcaac/molecules-30-02161-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/e82f8d2d7725/molecules-30-02161-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/642781d9a9b7/molecules-30-02161-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/48a2777637b7/molecules-30-02161-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/f9cac045f49a/molecules-30-02161-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/4aa02b6f6c52/molecules-30-02161-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/e83eac782fc6/molecules-30-02161-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/042bba3e1de0/molecules-30-02161-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/b7f87adc1f91/molecules-30-02161-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/724142027c6b/molecules-30-02161-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/f0cb3d69a63e/molecules-30-02161-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/6137d4d47599/molecules-30-02161-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/effcbb64d859/molecules-30-02161-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/26177c68f58d/molecules-30-02161-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/8bbf08a0180b/molecules-30-02161-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/f9e6c42fcaac/molecules-30-02161-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f85/12113889/e82f8d2d7725/molecules-30-02161-g014.jpg

相似文献

1
Advances in Superlattice Hydrogen Storage Alloys: Preparation Method, Phase Structure Modulation, and Hydrogen Storage Performance.超晶格储氢合金的研究进展：制备方法、相结构调控及储氢性能
Molecules. 2025 May 14;30(10):2161. doi: 10.3390/molecules30102161.
2
Influence of Zr Addition on the Microstructure and Hydrogenation Kinetics of TiVCrZr (x = 0, 5, 7, and 9) Alloys.添加Zr对TiVCrZr（x = 0、5、7和9）合金微观结构及氢化动力学的影响
Materials (Basel). 2024 Mar 16;17(6):1366. doi: 10.3390/ma17061366.
3
Tuning of Zr content in TiMn based multinary alloys by powder metallurgy to fabricate superior hydrogen storage properties.通过粉末冶金法调整钛锰基多元合金中的锆含量以制备具有优异储氢性能的合金。
J Colloid Interface Sci. 2025 Mar 15;682:1040-1050. doi: 10.1016/j.jcis.2024.12.043. Epub 2024 Dec 7.
4
Magnesium-Based Hydrogen Storage Alloys: Advances, Strategies, and Future Outlook for Clean Energy Applications.镁基储氢合金：清洁能源应用的进展、策略与未来展望
Molecules. 2024 May 27;29(11):2525. doi: 10.3390/molecules29112525.
5
V-Ti-Based Solid Solution Alloys for Solid-State Hydrogen Storage.用于固态储氢的钒钛基固溶体合金
Nanomicro Lett. 2025 Mar 4;17(1):175. doi: 10.1007/s40820-025-01672-w.
6
Rare-Earth Metal-Based Materials for Hydrogen Storage: Progress, Challenges, and Future Perspectives.用于储氢的稀土金属基材料：进展、挑战与未来展望
Nanomaterials (Basel). 2024 Oct 18;14(20):1671. doi: 10.3390/nano14201671.
7
Research Progress on the Oxidation Behavior of Ignition-Proof Magnesium Alloy and Its Effect on Flame Retardancy with Multi-Element Rare Earth Additions: A Review.多元素稀土添加阻燃镁合金的氧化行为及其对阻燃性影响的研究进展：综述
Materials (Basel). 2024 Jun 28;17(13):3183. doi: 10.3390/ma17133183.
8
Microstructure and hydrogen storage properties of the MgYNiCo (x = 0, 0.2, 0.3, and 0.4) alloys.MgYNiCo（x = 0、0.2、0.3和0.4）合金的微观结构与储氢性能
Sci Rep. 2024 Jan 9;14(1):905. doi: 10.1038/s41598-024-51602-w.
9
Influence of Fe on the Hydrogen Storage Properties of LaCeNi Alloys.Fe 对 LaCeNi 合金储氢性能的影响。
Langmuir. 2023 May 2;39(17):6061-6068. doi: 10.1021/acs.langmuir.3c00093. Epub 2023 Apr 20.
10
Superior hydrogen storage in high entropy alloys.高熵合金中优异的储氢性能。
Sci Rep. 2016 Nov 10;6:36770. doi: 10.1038/srep36770.

本文引用的文献

1
Intermetallic Compounds for Hydrogen Storage: Current Status and Future Perspectives.用于储氢的金属间化合物：现状与未来展望
Small. 2025 Apr;21(14):e2408889. doi: 10.1002/smll.202408889. Epub 2024 Nov 6.
2
Nanoscale engineering of solid-state materials for boosting hydrogen storage.用于提高储氢性能的固态材料的纳米级工程
Chem Soc Rev. 2024 Jan 22;53(2):972-1003. doi: 10.1039/d3cs00706e.
3
Nanostructuring of Mg-Based Hydrogen Storage Materials: Recent Advances for Promoting Key Applications.镁基储氢材料的纳米结构化：推动关键应用的最新进展
Nanomicro Lett. 2023 Apr 10;15(1):93. doi: 10.1007/s40820-023-01041-5.
4
Hydrogen Absorption Reactions of Hydrogen Storage Alloy LaNi under High Pressure.高压下储氢合金 LaNi 的氢气吸收反应。
Molecules. 2023 Jan 27;28(3):1256. doi: 10.3390/molecules28031256.
5
Strong yet ductile nanolamellar high-entropy alloys by additive manufacturing.通过增材制造得到强韧且延展的纳米层状高熵合金。
Nature. 2022 Aug;608(7921):62-68. doi: 10.1038/s41586-022-04914-8. Epub 2022 Aug 3.
6
Ammonia-Borane and Amine-Borane Dehydrogenation Mediated by Complex Metal Hydrides.复合金属氢化物介导的氨硼烷和胺硼烷脱氢。
Chem Rev. 2016 Aug 10;116(15):8848-72. doi: 10.1021/acs.chemrev.6b00043. Epub 2016 Apr 14.
7
Hydrogen storage in metal-organic frameworks.金属有机框架中的储氢
Chem Rev. 2012 Feb 8;112(2):782-835. doi: 10.1021/cr200274s. Epub 2011 Dec 22.
8
Synthesis and crystal structure of a Pr5Ni19 superlattice alloy and its hydrogen absorption-desorption property.Pr5Ni19 超晶格合金的合成及晶体结构及其吸放氢性能。
Inorg Chem. 2011 May 16;50(10):4548-52. doi: 10.1021/ic200253w. Epub 2011 Apr 18.
9
Storage of hydrogen, methane, and carbon dioxide in highly porous covalent organic frameworks for clean energy applications.用于清洁能源应用的高孔隙率共价有机框架中氢气、甲烷和二氧化碳的储存
J Am Chem Soc. 2009 Jul 1;131(25):8875-83. doi: 10.1021/ja9015765.