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钼酸铵磷酸盐复合材料用于去除重金属的研究进展:综述

Recent advances in the heavy metals removal using ammonium molybdophosphate composites: A review.

作者信息

Miyah Youssef, El Messaoudi Noureddine, Benjelloun Mohammed, Boualam Omar, Aasli Brahim, Graba Besma, Georgin Jordana, Alexandre-Franco María F, Knani Salah

机构信息

Laboratory of Materials, Processes, Catalysis, Agri-food, and Environment, Higher School of Technology, University Sidi Mohamed Ben Abdellah, Fez, Morocco; Ministry of Health and Social Protection, Higher Institute of Nursing Professions and Health Techniques, Fez, Morocco.

Laboratory of Materials, Processes, Catalysis, Agri-food, and Environment, Higher School of Technology, University Sidi Mohamed Ben Abdellah, Fez, Morocco; Faculty of Sciences, Ibn Zohr University, Agadir 80000, Morocco.

出版信息

Adv Colloid Interface Sci. 2025 Sep;343:103559. doi: 10.1016/j.cis.2025.103559. Epub 2025 May 26.

Abstract

Heavy metal contamination in water poses serious environmental and public health risks, driving advancements in remediation techniques. Ammonium molybdophosphate (AMP) composites have emerged as highly efficient adsorbents due to their ion-exchange capabilities, chemical stability, and specificity toward toxic metal ions. This review aims to synthesize recent scientific advances in the synthesis, functionalization, characterization, and application of AMP composites for heavy metal (HM) removal. It also emphasizes the technological, economic, and environmental challenges associated with their use and outlines future research directions to support their sustainable and effective large-scale implementation. The originality of this study lies in identifying advanced techniques for the functionalization of AMP composites, including hybrid approaches, while addressing regulatory, economic, and industrial aspects, to support a sustainable and circular scientific framework. This review emphasizes recent developments in AMP-based materials through the innovation of synthesis, functionalization, and hybridization with polymers and nanomaterials, which improve their adsorption efficiency and selectivity. The HMs' adsorption mechanism and integration of AMP composite into complicated water treatment systems will be probed. Scalability, regeneration, and multiple contaminant interactions are critically evaluated as limitations in addition to the synthesis cost of AMP composites. Further research efforts should optimize the AMP material to meet industrial-scale applications while using cost-effective means that offer a broader appeal toward environmental sustainability. AMP composites are highlighted as promising green and selective processes for heavy metal remediation.

摘要

水中的重金属污染对环境和公众健康构成严重风险,推动了修复技术的进步。钼酸铵磷酸盐(AMP)复合材料因其离子交换能力、化学稳定性以及对有毒金属离子的特异性,已成为高效吸附剂。本综述旨在综合近期关于AMP复合材料在重金属去除方面的合成、功能化、表征及应用的科学进展。它还强调了与使用AMP复合材料相关的技术、经济和环境挑战,并概述了未来的研究方向,以支持其可持续和有效的大规模应用。本研究的独特之处在于确定了AMP复合材料功能化的先进技术,包括混合方法,同时涉及监管、经济和工业方面,以支持可持续和循环的科学框架。本综述通过合成、功能化以及与聚合物和纳米材料的杂交创新,强调了基于AMP材料的最新进展,这些进展提高了它们的吸附效率和选择性。将探究重金属的吸附机制以及AMP复合材料在复杂水处理系统中的整合。除了AMP复合材料的合成成本外,还对可扩展性、再生以及多种污染物相互作用等作为限制因素进行了严格评估。进一步的研究应优化AMP材料以满足工业规模应用,同时采用具有成本效益的方法,这些方法对环境可持续性具有更广泛的吸引力。AMP复合材料被视为重金属修复有前景的绿色和选择性工艺。

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