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源自可持续资源的喷墨可打印导电活性炭墨水。

Inkjet Printable Conductive Activated Carbon Ink from Sustainable Sources.

作者信息

Vita Damasceno João Paulo, Annese Valerio Francesco, Coco Giulia, Kubota Lauro Tatsuo, Caironi Mario

机构信息

Center for Nano Science and Technology, Istituto Italiano di Tecnologia, Via Rubattino 81, Milan 20134, Italy.

Department of Analytical Chemistry, Institute of Chemistry, University of Campinas, Campinas, São Paulo 13084-971, Brazil.

出版信息

ACS Appl Electron Mater. 2025 May 6;7(10):4403-4412. doi: 10.1021/acsaelm.4c01509. eCollection 2025 May 27.

Abstract

Inkjet printing offers an attractive manufacturing method for flexible and large-area electronics, yet formulating sustainable inks not derived from fossil fuels represents a major challenge toward environmentally friendly technologies. Here, we present a conductive ink formulated for inkjet printing, consisting only of renewable and nontoxic components, namely electrically conductive activated carbon nanoparticles, ethyl cellulose as binder and stabilizer, and ethanol-terpineol mixture as the dispersant. The ink is composed of activated carbon nanoparticles with a diameter between 30 and 120 nm and exhibits high colloidal stability, dynamic viscosity and surface tension within an ideal range for inkjet printing. The ink produces electrically conductive patterns, achieving a resistivity of 6.6 Ω cm. Such result enables the manufacturing of printed resistive elements in electronic circuits, where the sheet resistance is tunable by the drop spacing and/or layers number of the printing process. As a proof-of-concept of future printed sustainable sensors, we employed this formulation to produce a resistive humidity sensor capable of detecting the moisture content in the air exhaled during respiration. The conductive ink herein presented is a step toward the quest for sustainable materials for environmentally friendly printed electronics.

摘要

喷墨打印为柔性和大面积电子产品提供了一种有吸引力的制造方法,然而,配制非化石燃料来源的可持续油墨是实现环境友好型技术的一项重大挑战。在此,我们展示了一种为喷墨打印配制的导电油墨,其仅由可再生且无毒的成分组成,即导电活性炭纳米颗粒、作为粘合剂和稳定剂的乙基纤维素,以及作为分散剂的乙醇 - 松油醇混合物。该油墨由直径在30至120纳米之间的活性炭纳米颗粒组成,在喷墨打印的理想范围内表现出高胶体稳定性、动态粘度和表面张力。该油墨能产生导电图案,电阻率达到6.6Ω·cm。这一结果使得在电子电路中制造印刷电阻元件成为可能,其中薄层电阻可通过打印过程中的墨滴间距和/或层数进行调节。作为未来印刷可持续传感器概念验证,我们采用这种配方生产了一种能够检测呼吸呼出空气中水分含量的电阻式湿度传感器。本文展示的导电油墨是朝着寻求用于环境友好型印刷电子产品的可持续材料迈出的一步。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3507/12120979/360fdf02bf4c/el4c01509_0001.jpg

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