真正的卡宾难题。
The Genuine Carbene Conundrum.
作者信息
Sawyer Bethany, Peltier Jesse L, Jazzar Rodolphe
机构信息
Department of Chemistry and Biochemistry, San Diego State University, 5500 Campanile Drive, San Diego, CA, 92182, USA.
Departments of Chemistry & Chemical Biology, and Chemical Engineering, Northeastern University, 360 Huntington Ave, Boston, MA, 02115, USA.
出版信息
Chemistry. 2025 Aug 7;31(44):e202501600. doi: 10.1002/chem.202501600. Epub 2025 Jun 25.
Carbenes, these neutral divalent carbon species have emerged as pivotal players in our laboratories. Despite their broad impact, direct characterization of these reactive molecules remains challenging in many cases. This concept article draws on recent literature to explore the strengths and limitations of the most widely used strategies for their identification.
卡宾，这些中性二价碳物种已在我们的实验室中成为关键角色。尽管它们具有广泛影响，但在许多情况下，对这些活性分子进行直接表征仍然具有挑战性。这篇概念文章借鉴近期文献，探讨了用于识别它们的最广泛使用策略的优势和局限性。
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