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用于先进储能应用的VSe和CuS纳米结构的协同集成

Synergistic integration of VSe and CuS nanostructures for advanced energy storage applications.

作者信息

Khan Imran, Arif Danish, Shah Atta Ullah, Safeen Kashif, Alotaibi Khalid M, Ali Basit, Girma Wubshet Mekonnen, Safeen Akif

机构信息

Department of Physics, University of Poonch Rawalakot, Rawalakot, 12350, Pakistan.

National Institute of Lasers and Optronics College, Pakistan Institute of Engineering and Applied Sciences, Nilore, Islamabad, 45650, Pakistan.

出版信息

Sci Rep. 2025 Jun 5;15(1):19761. doi: 10.1038/s41598-025-95088-6.

Abstract

The demand for sustainable energy storage has driven advancements in supercapacitors, known for their high-power density and rapid charge cycles. However, challenges like limited energy density and material stability must be addressed for practical applications. In this study, VSe/CuS nanocomposites were synthesized using a simple wet chemical method and investigated as electrode materials for supercapacitors. X-ray diffraction (XRD) analysis confirmed the phase purity of the materials while scanning electron microscopy (SEM) revealed spherical and flake-like morphology. The synergy between VSe's high electrical conductivity and CuS's pseudocapacitive properties enhances charge storage and electrochemical performance. The VSe/CuS electrode exhibited a high specific capacitance of 853.9 F/g at 1 A/g, outperforming individual VSe (395.6 F/g) and CuS (471.6 F/g). The VSe/CuS||AC device demonstrated a specific capacitance of 147.6 F/g, excellent rate capability, and 88.3% capacitance retention over 10,000 cycles at 10 A/g. These findings highlight the potential of VSe/CuS nanocomposites as high-performance electrode materials, advancing the development of next-generation energy storage technologies.

摘要

对可持续储能的需求推动了超级电容器的发展,超级电容器以其高功率密度和快速充电循环而闻名。然而,对于实际应用而言,能量密度有限和材料稳定性等挑战必须得到解决。在本研究中,采用简单的湿化学方法合成了VSe/CuS纳米复合材料,并将其作为超级电容器的电极材料进行了研究。X射线衍射(XRD)分析证实了材料的相纯度,而扫描电子显微镜(SEM)则揭示了球形和片状的形态。VSe的高电导率与CuS的赝电容特性之间的协同作用增强了电荷存储和电化学性能。VSe/CuS电极在1 A/g时表现出853.9 F/g的高比电容,优于单独的VSe(395.6 F/g)和CuS(471.6 F/g)。VSe/CuS||AC器件在10 A/g下表现出147.6 F/g的比电容、优异的倍率性能以及在10000次循环后88.3%的电容保持率。这些发现突出了VSe/CuS纳米复合材料作为高性能电极材料的潜力,推动了下一代储能技术的发展。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb56/12141592/84705123c9ba/41598_2025_95088_Fig1_HTML.jpg

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