• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

探索高级并苯的化学：从合成到应用。

Exploring the chemistry of higher acenes: from synthesis to applications.

作者信息

Hayashi Hironobu, Yamada Hiroko

机构信息

Center for Basic Research on Materials, National Institute for Materials Science (NIMS) 1-2-1 Sengen Tsukuba Ibaraki 305-0047 Japan

Institute for Chemical Research, Kyoto University Gokasho Uji Kyoto 611-0011 Japan

出版信息

Chem Sci. 2025 Jun 4;16(25):11204-11231. doi: 10.1039/d5sc02422f. eCollection 2025 Jun 25.

DOI:10.1039/d5sc02422f
PMID:40474956
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12135676/
Abstract

This review explores the advancements in the chemistry of higher acenes and their derivatives, with a focus on their synthesis, characterization, and potential applications. Historically, higher acenes have presented challenges to study due to their inherent instability and reactivity under ambient conditions. However, innovative synthetic strategies, including on-surface synthesis and the precursor approach, have significantly contributed to the ability to synthesize higher acenes even at preparative scales while evaluating their magnetic and semiconducting properties. Furthermore, ethynylene-bridged acene oligomers and polymers, known for their extended π-conjugated systems, have shown promise not only as semiconducting materials but also as topological materials. As synthetic methods continue to evolve and characterization techniques become more sophisticated, higher acenes offer exciting opportunities for progress in the fields of organic chemistry and materials science, paving the way for advanced applications in organic electronics.

摘要

本综述探讨了高级并苯及其衍生物的化学进展，重点关注其合成、表征和潜在应用。从历史上看，高级并苯由于其在环境条件下固有的不稳定性和反应性，给研究带来了挑战。然而，创新的合成策略，包括表面合成和前驱体方法，即使在制备规模下合成高级并苯并评估其磁性和半导体性质方面也做出了重大贡献。此外，以其扩展的π共轭体系而闻名的乙炔桥连并苯低聚物和聚合物，不仅作为半导体材料，而且作为拓扑材料都显示出了前景。随着合成方法不断发展，表征技术变得更加精密，高级并苯为有机化学和材料科学领域的进展提供了令人兴奋的机会，为有机电子学中的先进应用铺平了道路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/2d8633c3f2e2/d5sc02422f-p2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/4a06bcbec951/d5sc02422f-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/e52fe072affa/d5sc02422f-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/f585aa6dec52/d5sc02422f-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/42023505091b/d5sc02422f-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/0ab246662303/d5sc02422f-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/304fc02118ef/d5sc02422f-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/7bbbd9f51a27/d5sc02422f-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/c7763f364149/d5sc02422f-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/520eba43c6c1/d5sc02422f-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/4c7e1c5f6bf3/d5sc02422f-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/d9c798f99269/d5sc02422f-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/78d2eb23e7d8/d5sc02422f-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/1de1805a5418/d5sc02422f-f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/01632f98d8b3/d5sc02422f-f14.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/d22a5ec88cfa/d5sc02422f-f15.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/49dd5c841e10/d5sc02422f-f16.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/b1d651309733/d5sc02422f-f17.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/d317ed8d0bd1/d5sc02422f-f18.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/b74274502dd1/d5sc02422f-f19.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/909f1f65bd3a/d5sc02422f-f20.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/93c2bee363c6/d5sc02422f-f21.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/38254e53dd56/d5sc02422f-f22.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/69ccffd238c7/d5sc02422f-f23.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/d49390fa9f73/d5sc02422f-f24.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/a509473c0549/d5sc02422f-f25.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/57bde12a8645/d5sc02422f-f26.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/de55220052ac/d5sc02422f-f27.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/bcf9ac57a495/d5sc02422f-f28.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/c5bd2e5662e7/d5sc02422f-f29.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/aa2aeff0b32e/d5sc02422f-f30.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/093e7c3bf87f/d5sc02422f-f31.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/0f49ea450c8b/d5sc02422f-f32.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/ee9466082d38/d5sc02422f-f33.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/0cc2e7356e2b/d5sc02422f-f34.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/399ae8688a41/d5sc02422f-f35.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/7bb4d6fda687/d5sc02422f-f36.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/d78fa6b497f0/d5sc02422f-f37.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/5913f03a5971/d5sc02422f-f38.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/a5522ab3dfa1/d5sc02422f-f39.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/9ccc9f3b8863/d5sc02422f-f40.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/2da95ab6d532/d5sc02422f-f41.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/d7ffa8d384a3/d5sc02422f-f42.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/b4c568e53815/d5sc02422f-f43.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/34697922a23d/d5sc02422f-f44.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/b77282fa6a3a/d5sc02422f-f45.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/08d71a2ced63/d5sc02422f-f46.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/e7af2cd04a76/d5sc02422f-p1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/2d8633c3f2e2/d5sc02422f-p2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/4a06bcbec951/d5sc02422f-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/e52fe072affa/d5sc02422f-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/f585aa6dec52/d5sc02422f-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/42023505091b/d5sc02422f-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/0ab246662303/d5sc02422f-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/304fc02118ef/d5sc02422f-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/7bbbd9f51a27/d5sc02422f-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/c7763f364149/d5sc02422f-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/520eba43c6c1/d5sc02422f-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/4c7e1c5f6bf3/d5sc02422f-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/d9c798f99269/d5sc02422f-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/78d2eb23e7d8/d5sc02422f-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/1de1805a5418/d5sc02422f-f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/01632f98d8b3/d5sc02422f-f14.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/d22a5ec88cfa/d5sc02422f-f15.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/49dd5c841e10/d5sc02422f-f16.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/b1d651309733/d5sc02422f-f17.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/d317ed8d0bd1/d5sc02422f-f18.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/b74274502dd1/d5sc02422f-f19.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/909f1f65bd3a/d5sc02422f-f20.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/93c2bee363c6/d5sc02422f-f21.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/38254e53dd56/d5sc02422f-f22.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/69ccffd238c7/d5sc02422f-f23.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/d49390fa9f73/d5sc02422f-f24.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/a509473c0549/d5sc02422f-f25.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/57bde12a8645/d5sc02422f-f26.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/de55220052ac/d5sc02422f-f27.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/bcf9ac57a495/d5sc02422f-f28.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/c5bd2e5662e7/d5sc02422f-f29.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/aa2aeff0b32e/d5sc02422f-f30.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/093e7c3bf87f/d5sc02422f-f31.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/0f49ea450c8b/d5sc02422f-f32.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/ee9466082d38/d5sc02422f-f33.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/0cc2e7356e2b/d5sc02422f-f34.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/399ae8688a41/d5sc02422f-f35.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/7bb4d6fda687/d5sc02422f-f36.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/d78fa6b497f0/d5sc02422f-f37.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/5913f03a5971/d5sc02422f-f38.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/a5522ab3dfa1/d5sc02422f-f39.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/9ccc9f3b8863/d5sc02422f-f40.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/2da95ab6d532/d5sc02422f-f41.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/d7ffa8d384a3/d5sc02422f-f42.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/b4c568e53815/d5sc02422f-f43.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/34697922a23d/d5sc02422f-f44.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/b77282fa6a3a/d5sc02422f-f45.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/08d71a2ced63/d5sc02422f-f46.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/e7af2cd04a76/d5sc02422f-p1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ddb/12189268/2d8633c3f2e2/d5sc02422f-p2.jpg

相似文献

1
Exploring the chemistry of higher acenes: from synthesis to applications.探索高级并苯的化学：从合成到应用。
Chem Sci. 2025 Jun 4;16(25):11204-11231. doi: 10.1039/d5sc02422f. eCollection 2025 Jun 25.
2
Survivor, family and professional experiences of psychosocial interventions for sexual abuse and violence: a qualitative evidence synthesis.性虐待和暴力的心理社会干预的幸存者、家庭和专业人员的经验：定性证据综合。
Cochrane Database Syst Rev. 2022 Oct 4;10(10):CD013648. doi: 10.1002/14651858.CD013648.pub2.
3
Systemic pharmacological treatments for chronic plaque psoriasis: a network meta-analysis.慢性斑块状银屑病的全身药理学治疗：一项网状荟萃分析。
Cochrane Database Syst Rev. 2017 Dec 22;12(12):CD011535. doi: 10.1002/14651858.CD011535.pub2.
4
Systemic pharmacological treatments for chronic plaque psoriasis: a network meta-analysis.系统性药理学治疗慢性斑块状银屑病：网络荟萃分析。
Cochrane Database Syst Rev. 2021 Apr 19;4(4):CD011535. doi: 10.1002/14651858.CD011535.pub4.
5
Primary Amine-Based Photoclick Chemistry: From Concept to Diverse Applications in Chemical Biology and Medicinal Chemistry.基于伯胺的光点击化学：从概念到化学生物学和药物化学中的多样应用
Acc Chem Res. 2025 Jun 18. doi: 10.1021/acs.accounts.5c00158.
6
Home treatment for mental health problems: a systematic review.心理健康问题的居家治疗：一项系统综述
Health Technol Assess. 2001;5(15):1-139. doi: 10.3310/hta5150.
7
A rapid and systematic review of the clinical effectiveness and cost-effectiveness of topotecan for ovarian cancer.拓扑替康治疗卵巢癌的临床有效性和成本效益的快速系统评价。
Health Technol Assess. 2001;5(28):1-110. doi: 10.3310/hta5280.
8
Prophylactic mastectomy for the prevention of breast cancer.预防性乳房切除术用于预防乳腺癌。
Cochrane Database Syst Rev. 2004 Oct 18(4):CD002748. doi: 10.1002/14651858.CD002748.pub2.
9
The use of Open Dialogue in Trauma Informed Care services for mental health consumers and their family networks: A scoping review.创伤知情护理服务中使用开放对话模式为心理健康消费者及其家庭网络提供服务：范围综述。
J Psychiatr Ment Health Nurs. 2024 Aug;31(4):681-698. doi: 10.1111/jpm.13023. Epub 2024 Jan 17.
10
How lived experiences of illness trajectories, burdens of treatment, and social inequalities shape service user and caregiver participation in health and social care: a theory-informed qualitative evidence synthesis.疾病轨迹的生活经历、治疗负担和社会不平等如何影响服务使用者和照顾者参与健康和社会护理：一项基于理论的定性证据综合分析
Health Soc Care Deliv Res. 2025 Jun;13(24):1-120. doi: 10.3310/HGTQ8159.

本文引用的文献

1
On-Surface Synthesis and Characterization of Pentadecacene and Its Gold Complexes.并五苯及其金配合物的表面合成与表征
J Am Chem Soc. 2025 Feb 12;147(6):4862-4870. doi: 10.1021/jacs.4c13296. Epub 2025 Jan 17.
2
The Journey for the Synthesis of Large Acenes.大并苯的合成之旅。
Chemistry. 2024 Oct 11;30(57):e202402122. doi: 10.1002/chem.202402122. Epub 2024 Sep 23.
3
How to Stabilize Large Soluble (Hetero-)Acenes.如何稳定大型可溶性（杂）并苯。
J Am Chem Soc. 2024 Jun 26;146(25):16937-16949. doi: 10.1021/jacs.4c03484. Epub 2024 Jun 11.
4
Stabilizing Azaheptacenes.稳定氮杂七并苯
J Am Chem Soc. 2024 Mar 6;146(9):5793-5798. doi: 10.1021/jacs.3c13629. Epub 2024 Feb 27.
5
Bistability between π-diradical open-shell and closed-shell states in indeno[1,2-a]fluorene.茚并[1,2-a]芴中π-双自由基开壳态与闭壳态之间的双稳态
Nat Chem. 2024 May;16(5):755-761. doi: 10.1038/s41557-023-01431-7. Epub 2024 Feb 8.
6
Molecular Graphene Nanoribbon Junctions.分子石墨烯纳米带结
J Am Chem Soc. 2024 Feb 14;146(6):3963-3973. doi: 10.1021/jacs.3c11340. Epub 2024 Feb 2.
7
Synthesis of Tridecacene by Multistep Single-Molecule Manipulation.通过多步单分子操纵合成十三并苯。
J Am Chem Soc. 2024 Feb 14;146(6):3700-3709. doi: 10.1021/jacs.3c09392. Epub 2024 Jan 12.
8
On-Surface Synthesis and Determination of the Open-Shell Singlet Ground State of Tridecacene.十三并苯的表面合成及开壳单重基态的测定
Angew Chem Int Ed Engl. 2024 Feb 26;63(9):e202317091. doi: 10.1002/anie.202317091. Epub 2024 Jan 24.
9
On-Surface Synthesis of Edge-Extended Zigzag Graphene Nanoribbons.边缘扩展之字形石墨烯纳米带的表面合成
Adv Mater. 2023 Nov;35(48):e2306311. doi: 10.1002/adma.202306311. Epub 2023 Oct 25.
10
Modulating Strain in Twisted Pyrene-Fused Azaacenes.调控扭曲的芘并氮杂蒽中的应变
Chemistry. 2023 Dec 11;29(69):e202302002. doi: 10.1002/chem.202302002. Epub 2023 Oct 25.