Khan M Ajmal, Matsuura Eriko, Kashima Yukio, Hirayama Hideki
RIKEN Pioneering Research Institute (PRI), 2-1 Hirosawa, Wako, Saitama, 351-0198, Japan.
Sci Rep. 2025 Jun 6;15(1):19972. doi: 10.1038/s41598-025-03746-6.
The external-quantum efficiency (EQE) of AlGaN-based ultraviolet-B light-emitting diodes (UVB LEDs) has achieved a world record value of 9.6% on wafers but suffers from a low light extraction efficiency (LEE) of < 15%, notably lower than that of the LEE of InGaN blue LEDs (> 89%). This study employed the finite-difference time-domain (FDTD) method to explore how micro-patterned c-plane Sapphire substrates (microPSS) or nano-patterned c-plane Sapphire substrates (nanoPSSs) and reflecting photonic crystals (R-PhCs) influence light scattering in flip-chipped AlGaN-based UVB LEDs, with or without an Al-side reflector. First, various microPSS and nanoPSS shapes (Pillar-like and Hole-like) were analysed by the FDTD to optimise the pitch (a), diameter (d), height (h), and diffraction order (m) under Bragg's condition. The nanoPSS were found most effective for UVB LEDs at an emission peak of 304 nm with cylindrical Hole-like nanoPSS (m = 10, d = 596 nm, a = 746 nm, h = 500 nm, R/a = 0.38), (R is the radius of the holes of the nanoPSS or PhC) improving LEE enhancement to the maximum possible value of approximately 18%. Next, an Al-side reflector was introduced to evaluate the combined impact of optimised nanoPSS and R-PhC (Hole-like) on theoretical light extraction. Parameters (m = 3; h = 150 nm; R/a = 0.40) applied in p-GaN or p-AlGaN contact layers boosted light extraction to approximately 148% or 150% (with an Al-side reflector) and approximately 120% (without an Al-side reflector), marking significant theoretical and experimental advancements in AlGaN UVB LED efficiency.
基于AlGaN的紫外B光发射二极管(UVB LED)的外量子效率(EQE)在晶圆上已达到9.6%的世界纪录值,但光提取效率(LEE)较低,低于15%,明显低于InGaN蓝光LED的LEE(>89%)。本研究采用时域有限差分(FDTD)方法,探讨微图案化c面蓝宝石衬底(microPSS)或纳米图案化c面蓝宝石衬底(nanoPSS)以及反射光子晶体(R-PhC)如何影响倒装芯片式基于AlGaN的UVB LED中的光散射,有无Al侧反射器的情况均进行了研究。首先,通过FDTD分析了各种microPSS和nanoPSS形状(柱状和孔状),以在布拉格条件下优化间距(a)、直径(d)、高度(h)和衍射级(m)。发现纳米图案化c面蓝宝石衬底对于发射峰值为304 nm的UVB LED最为有效,圆柱形孔状纳米图案化c面蓝宝石衬底(m = 10,d = 596 nm,a = 746 nm,h = 500 nm,R/a = 0.38)(R是纳米图案化c面蓝宝石衬底或光子晶体的孔半径)将光提取效率提高到约18%的最大值。接下来,引入Al侧反射器以评估优化的纳米图案化c面蓝宝石衬底和反射光子晶体(孔状)对理论光提取的综合影响。应用于p-GaN或p-AlGaN接触层的参数(m = 3;h = 150 nm;R/a = 0.40)将光提取提高到约148%或150%(有Al侧反射器时)和约120%(无Al侧反射器时),标志着AlGaN UVB LED效率在理论和实验方面取得了显著进展。