Jamshidi Elmira, Rajai-Daryasarei Saideh, Bijanzadeh Hamid Reza, Ariafard Alireza, Balalaie Saeed
Peptide Chemistry Research Institute, K. N. Toosi University of Technology, P.O. Box 15875-4416, Tehran, Iran.
Department of Environmental Sciences, Faculty of Natural Resources and Marine Sciences, Tarbiat Modares University, P.O. Box 46414-356, Noor, Iran.
Org Biomol Chem. 2025 Jul 2;23(26):6400-6405. doi: 10.1039/d5ob00816f.
We report herein an approach for synthesizing cyclopropane derivatives in moderate to very good yields through the Cu-catalyzed radical cyclization of 1,6-enynes in the presence of TBHP as both the oxidant and oxygen atom source. The advantages of this reaction are the formation of three chemical bonds using a simple copper catalyst/TBHP system as well as mild reaction conditions.
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