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为未来提供动力:揭示钠、钾和镁固态电池的潜力。

Powering the Future: Unveiling the Potential of Na, K, and Mg Solid-State Batteries.

作者信息

Shang Ruoxu, Ma Yi, Anduaga-Quiros Kathrine, Briseno Gustavo, Ning Yuying, Chang Hung-Ju, Ozkan Mihrimah, Ozkan Cengiz S

机构信息

Materials Science and Engineering Program, University of California Riverside, Riverside, CA 92521, USA.

Department of Mechanical Engineering, University of California Riverside, Riverside, CA 92521, USA.

出版信息

Nanomaterials (Basel). 2025 Jun 3;15(11):859. doi: 10.3390/nano15110859.

DOI:10.3390/nano15110859
PMID:40497905
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12157871/
Abstract

In the pursuit of advancing sustainable energy storage solutions, solid-state batteries (SSBs) have emerged as a formidable contender to traditional lithium-ion batteries, distinguished by their superior energy density, augmented safety measures, and improved cyclability. Amid escalating concerns regarding resource scarcity, environmental ramifications, and the safety hazards posed by lithium-ion technologies, the exploration into non-lithium SSBs has emerged as a crucial frontier for technological breakthroughs. This exhaustive review delves into the latest progressions and persisting challenges within the sphere of sodium (Na), potassium (K), and magnesium (Mg) SSBs, spotlighting seminal materials, cutting-edge technologies, and strategic approaches propelling advancements in this vibrant domain. Despite considerable progress, hurdles such as amplifying ionic conductivity, mitigating the intricacies at the electrode-electrolyte interface, and realizing scalable production methodologies continue to loom. Nevertheless, the trajectory for non-lithium SSBs holds considerable promise, poised to redefine the landscape of electric vehicles, portable electronics, and grid stabilization technologies, thereby marking a significant leap toward realizing a sustainable and energy-secure future. This review article aims to provide a detailed overview of the materials and methodologies underpinning the development of these next-generation energy storage devices, underscoring their potential to catalyze a paradigm shift in our approach to energy storage and utilization.

摘要

在推进可持续储能解决方案的过程中,固态电池(SSB)已成为传统锂离子电池的有力竞争者,其特点是具有更高的能量密度、增强的安全措施和更好的循环性能。在对资源稀缺、环境影响以及锂离子技术带来的安全隐患的担忧不断升级的背景下,对非锂固态电池的探索已成为实现技术突破的关键前沿领域。这篇详尽的综述深入探讨了钠(Na)、钾(K)和镁(Mg)固态电池领域的最新进展和持续存在的挑战,重点介绍了推动这一充满活力领域发展的重要材料、前沿技术和战略方法。尽管取得了显著进展,但诸如提高离子电导率、减轻电极 - 电解质界面的复杂性以及实现可扩展的生产方法等障碍仍然存在。然而,非锂固态电池的发展前景广阔,有望重新定义电动汽车、便携式电子产品和电网稳定技术的格局,从而朝着实现可持续和能源安全的未来迈出重要一步。这篇综述文章旨在详细概述支撑这些下一代储能设备发展的材料和方法,强调它们在推动我们储能和利用方式发生范式转变方面的潜力。

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Adv Mater. 2025 Jul;37(30):e2503107. doi: 10.1002/adma.202503107. Epub 2025 May 19.
2
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3
Preparation and Application of Thin-Sodium Metal.薄钠金属的制备与应用
Small Sci. 2024 Mar 19;4(6):2300362. doi: 10.1002/smsc.202300362. eCollection 2024 Jun.
4
Fluorinated amorphous halides with improved ionic conduction and stability for all-solid-state sodium-ion batteries.具有改善的离子传导性和稳定性的用于全固态钠离子电池的氟化非晶卤化物。
Nat Commun. 2025 Mar 21;16(1):2808. doi: 10.1038/s41467-025-58113-w.
5
Multi-Level Engineering from Surface to Bulk Enabling Highly Stable Ni-Rich O3-Type Cathode toward Temperature-Tolerant Quasi-Solid-State Na-Ion Batteries.
Small. 2025 Apr;21(14):e2412537. doi: 10.1002/smll.202412537. Epub 2025 Feb 25.
6
High-Energy, High-Power Sodium-Ion Batteries from a Layered Organic Cathode.基于层状有机阴极的高能、高功率钠离子电池
J Am Chem Soc. 2025 Feb 19;147(7):6181-6192. doi: 10.1021/jacs.4c17713. Epub 2025 Feb 4.
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Revisiting Intercalation Anode Materials for Potassium-Ion Batteries.重新审视用于钾离子电池的嵌入型负极材料
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