Wang Zhengming, Wang Fengqiujie, Lin Liu, Tao Ningping
College of Food Science and Technology, Shanghai Ocean University, Shanghai 201306, PR China.
College of Food Science and Technology, Shanghai Ocean University, Shanghai 201306, PR China; Shanghai Engineering Research Center of Aquatic-Product Processing & Preservation, Shanghai 201306, PR China; National Experimental Teaching Demonstration Center for Food Science and Engineering, Shanghai Ocean University, Shanghai, PR China.
Int J Biol Macromol. 2025 Jul;318(Pt 2):145103. doi: 10.1016/j.ijbiomac.2025.145103. Epub 2025 Jun 9.
Tuna oil represents a significant source of ω-3 fatty acids, most notably eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA). However, its unique fishy flavor may affect consumer acceptance. V-type Starch (VGS), distinguished by its distinctive single-helical structure, demonstrates a selective adsorption capacity for volatile odor molecules. This research explores the effects of ultrasound treatment (0 W, 160 W, 240 W, 320 W, 400 W) on the structural and functional properties of VGS and evaluates its potential application as a deodorizing material for tuna oil. The results indicate that ultrasound modification improved the single helix structure, increased crystallinity, and created a porous surface morphology in VGS, contributing to its outstanding adsorption properties. At an ultrasound power of 240 W, the relative crystallinity of VGS increases from 29.32 % to 45.99 %, accompanied by the development of numerous pores and fissures on the surface. The gas chromatography-ion mobility spectrometry (GC-IMS) and E-nose analyses demonstrate that ultrasound treatment at 240 W achieves the most effective deodorization of tuna oil, with adsorption efficiencies of 71.7 % for aldehydes and 73.29 % for alcohols, and a significant reduction in odor intensity (p < 0.05). Thus, the ultrasound modification VGS serves as a high-performance, environmentally friendly starch-based adsorbent with potential applications in deodorizing tuna oil.
金枪鱼油是ω-3脂肪酸的重要来源,最显著的是二十碳五烯酸(EPA)和二十二碳六烯酸(DHA)。然而,其独特的鱼腥味可能会影响消费者的接受度。V型淀粉(VGS)以其独特的单螺旋结构为特征,对挥发性气味分子具有选择性吸附能力。本研究探讨了超声处理(0W、160W、240W、320W、400W)对VGS结构和功能特性的影响,并评估其作为金枪鱼油除臭材料的潜在应用。结果表明,超声改性改善了VGS的单螺旋结构,增加了结晶度,并形成了多孔表面形态,有助于其出色的吸附性能。在240W的超声功率下,VGS的相对结晶度从29.32%增加到45.99%,同时表面出现大量孔隙和裂缝。气相色谱-离子迁移谱(GC-IMS)和电子鼻分析表明,240W的超声处理对金枪鱼油的除臭效果最为显著,对醛类的吸附效率为71.7%,对醇类的吸附效率为73.29%,气味强度显著降低(p<0.05)。因此,超声改性的VGS作为一种高性能、环境友好的淀粉基吸附剂,在金枪鱼油除臭方面具有潜在应用价值。