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Order-Disorder-Type Transitions Through a Multifractal Procedure in Cu-Zn-Al Alloys-Experimental and Theoretical Design.

作者信息

Plăcintă Constantin, Nedeff Valentin, Panainte-Lehăduş Mirela, Puiu Costescu Elena, Petrescu Tudor-Cristian, Stanciu Sergiu, Agop Maricel, Mirilă Diana-Carmen, Nedeff Florin

机构信息

Department of Materials Science, Faculty of Material Science and Engineering, "Gheorghe Asachi" Technical University of Iasi, Blvd. Prof. Dr. D. Mangeron, No. 41, 700050 Iași, Romania.

Department of Industrial Systems Engineering and Management, Faculty of Engineering, "Vasile Alecsandri" University of Bacau, 157, Calea Marasesti, 600115 Bacau, Romania.

出版信息

Entropy (Basel). 2025 May 30;27(6):587. doi: 10.3390/e27060587.

Abstract

Experimental and theoretical design on thermal and structural properties of Cu-Zn-Al alloys are established. As such, from an experimental point of view, differential thermal analysis has been performed with the help of a DSC Netzsch STA 449 F1 Jupiter calorimeter with high levels of sensitivity, and the structural analysis has been accomplished through X-ray diffraction and SEM analysis. An unusual specific property for a metallic material has been discovered, which is known as "rubber-type behavior", a characteristic determined by micro-structural changes. From the theoretical point of view, the thermal transfer in Cu-Zn-Al is presented by assimilating this alloy, both structurally and functionally, with a multifractal, situation in which the order-disorder transitions assimilated with thermal "dynamics" of Cu-Zn-Al, are mimed through transitions from non-multifractal to multifractal curves. In such a context, the thermal expansion velocity contains both the propagation speed of the phase transformation (be it a direct one: austenitic-martensitic transformation, or an indirect one: martensitic-austenitic transformation) and the thermal diffusion speed. Then, through self-modulations of the thermal field, the Cu-Zn-Al alloy will self-structure in channel-type or cellular-type thermal patterns, which can be linked to obtained experimental data. Consequently, since the thermal conductivity becomes a function of the observation scale, and heat transfer is modified to reflect the multifractal, non-differentiable paths in the material, it leads to anomalous diffusion and complex thermal behaviors.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f6db/12192012/a5d4f07bc378/entropy-27-00587-g001.jpg

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