Dias Josinaldo O, Siqueira Rayara Davel, Coelho Bruno Fonseca, Conceição Amanda O
Agricultural Sciences and Engineering Center, Federal University of Espírito Santo, Alegre 29500-000, Brazil.
Materials (Basel). 2025 Jun 11;18(12):2746. doi: 10.3390/ma18122746.
Naturally reinforced polymer composites have emerged as a promising sustainable alternative to conventional polymers due to their biodegradability. This study aimed to develop a composite by incorporating charcoal particulate into a recycled high-density polyethylene (HDPE) matrix and evaluating its mechanical properties. Two manufacturing methods (compression molding and extrusion) and four charcoal concentrations (0, 5, 10, and 15%) were investigated. Characterization involved tensile tests and non-destructive evaluation using wave propagation and ultrasound techniques. The experiment followed a completely randomized design with a 4 × 2 factorial arrangement, comprising eight treatments. Statistical analysis was conducted using Tukey's test for multiple comparisons. The tensile test results indicated that the manufacturing methods of compression molding and extrusion led to significant differences in the elastic modulus (MOE) variable, in contrast to the results observed for the maximum stress variable. However, the addition of charcoal particulate caused a notable reduction in maximum tensile strength (approximately 50%), from 20.17 to 11.19 MPa, and a 22% decrease in the MOE, from 310.93 to 242.88 MPa, compared to unreinforced HDPE. Non-destructive testing confirmed the tensile test findings, also indicating a reduction in MOE. Despite the decline in mechanical properties, these composites remain viable for applications prioritizing lightweight structures, thermal insulation, or chemical resistance. Furthermore, their use enhances the valorization of waste and increases sustainability by reducing environmental impact.
由于其生物可降解性,天然增强聚合物复合材料已成为传统聚合物一种有前景的可持续替代品。本研究旨在通过将木炭颗粒掺入回收的高密度聚乙烯(HDPE)基体中并评估其力学性能来开发一种复合材料。研究了两种制造方法(压缩成型和挤出)和四种木炭浓度(0%、5%、10%和15%)。表征包括拉伸试验以及使用波传播和超声技术的无损评估。实验采用完全随机设计,具有4×2析因安排,包括八种处理。使用Tukey检验进行多重比较的统计分析。拉伸试验结果表明,与最大应力变量的结果相比,压缩成型和挤出的制造方法在弹性模量(MOE)变量上导致了显著差异。然而,与未增强的HDPE相比,添加木炭颗粒导致最大拉伸强度显著降低(约50%),从20.17MPa降至11.19MPa,MOE降低22%,从310.93MPa降至242.88MPa。无损检测证实了拉伸试验结果,也表明MOE降低。尽管力学性能有所下降,但这些复合材料对于优先考虑轻质结构、隔热或耐化学性的应用仍然可行。此外,它们的使用提高了废物的价值,并通过减少环境影响提高了可持续性。