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纤维素纳米纤维处理木材的物理力学及吸附性能

Physico-Mechanical and Sorption Properties of Wood Treated with Cellulose Nanofibers.

作者信息

Woźniak Magdalena, Majka Jerzy, Krystofiak Tomasz, Lis Barbara, Roszyk Edward, Ratajczak Izabela

机构信息

Department of Chemistry, Faculty of Forestry and Wood Technology, Poznan University of Life Sciences, Wojska Polskiego 75, 60625 Poznan, Poland.

Department of Wood Science and Thermal Techniques, Faculty of Forestry and Wood Technology, Poznan University of Life Sciences, Wojska Polskiego 28, 60637 Poznan, Poland.

出版信息

Materials (Basel). 2025 Jun 12;18(12):2762. doi: 10.3390/ma18122762.

Abstract

This paper presents the effect of wood treatment with cellulose nanofibers on its parameters. The wettability, color changes (also after UV+IR radiation), equilibrium moisture content and mechanical parameters of wood treated with cellulose nanofibers (CNF) in three concentrations (0.5, 1 and 2%) were determined. Wood treatment with CNF increased the wettability of its surface, as evidenced by lower values of the contact angle (24.3-56.3 degrees) compared to untreated wood (98.3 degrees). The SEM images indicated the formation of cellulose nanofiber networks on the wood surface, especially in the case of 2% CNF-treated wood, which formed a well-adhered and homogenous film. Wood treated with 0.5% CNF showed a lower total color change (∆*) value (1.9) after aging compared to untreated wood (2.9), indicating that the color changes in the treated wood were very small and recognizable only to an experienced observer, while the color differences in the control wood were recognizable to an inexperienced observer. Furthermore, CNF showed no negative effect on the strength parameters of the treated wood and only slightly affected the equilibrium moisture content for both sorption phases over the entire relative humidity range compared to control samples. The results prove the effective use of cellulose nanofibers in wood treatment, which can be an ecological and non-toxic component of wood protection systems.

摘要

本文介绍了用纤维素纳米纤维处理木材对其各项参数的影响。测定了用三种浓度(0.5%、1%和2%)的纤维素纳米纤维(CNF)处理的木材的润湿性、颜色变化(紫外线+红外线辐射后)、平衡含水率和力学参数。用CNF处理木材提高了其表面的润湿性,与未处理木材(98.3度)相比,接触角值较低(24.3-56.3度)证明了这一点。扫描电子显微镜图像表明在木材表面形成了纤维素纳米纤维网络,特别是在2% CNF处理的木材中,形成了附着力良好且均匀的薄膜。与未处理木材(2.9)相比,用0.5% CNF处理的木材在老化后的总颜色变化(∆*)值较低(1.9),这表明处理过的木材颜色变化非常小,只有经验丰富的观察者才能识别,而对照木材的颜色差异无经验的观察者也能识别。此外,与对照样品相比,CNF对处理过的木材的强度参数没有负面影响,并且在整个相对湿度范围内对两个吸附阶段的平衡含水率仅略有影响。结果证明了纤维素纳米纤维在木材处理中的有效应用,它可以成为木材保护系统的一种生态且无毒的成分。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b814/12195487/84fd5d02f6f3/materials-18-02762-g001.jpg

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