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用于光催化、能量产生和超级电容器应用的SnS/MWCNT异质结构的性能改进。

Improved performance of SnS/MWCNT heterostructures for photocatalytic, energy generation and supercapacitors applications.

作者信息

Sakthi P, Uma J, Balraj B, Arulvendhan K

机构信息

Department of Electronics and Communication Engineering, M Kumarasamy College of Engineering, Karur, 639113, India.

Department of Electrical and Electronics Engineering, M Kumarasamy College of Engineering, Karur, 639113, India.

出版信息

Sci Rep. 2025 Jul 2;15(1):22747. doi: 10.1038/s41598-025-07281-2.

Abstract

Semiconductor/graphene allotropes have shown remarkable performance in energy applications in recent years. Efficient visible-light-performance SnS/MWCNT photocatalytic heterostructured nanomaterials were prepared using a simple ultrasonic technique. A tetragonal MWCNT crystal structure and an orthorhombic SnS crystal structure were identified in the composite material through structural research. The uniformly distributed 5 nm SnS nanoparticles on the MWCNT nanosheet surface were visible in TEM images.The addition of SnS nanoparticles to MWCNT resulted in improved visible-light absorption, as proven by UV-vis absorption spectroscopy tests, highlighting its technological significance. The composites produced greater supercapacitance of 1611.89 F/g, 1523.89 F/g, and 1453.2 F/g for 0.5 A/g current density for various concentrations of MWCNT, according to electrochemical measurements. The higher efficiency of 13.1% was evident in photovoltaic experiments using the nanocomposite.It also exhibited an excellent photodegradation efficiency of about 90%. It was found that the nanocomposite's efficiency was greater than that of pure SnS and MWCNT.

摘要

近年来,半导体/石墨烯同素异形体在能源应用中表现出卓越性能。采用简单的超声技术制备了高效可见光性能的SnS/MWCNT光催化异质结构纳米材料。通过结构研究在复合材料中鉴定出四方晶系的MWCNT晶体结构和正交晶系的SnS晶体结构。在透射电镜图像中可以看到MWCNT纳米片表面均匀分布着5纳米的SnS纳米颗粒。紫外可见吸收光谱测试证明,向MWCNT中添加SnS纳米颗粒可改善可见光吸收,突出了其技术意义。电化学测量结果表明,对于不同浓度的MWCNT,在0.5 A/g电流密度下,复合材料产生的超级电容分别为1611.89 F/g、1523.89 F/g和1453.2 F/g。在使用该纳米复合材料的光伏实验中,明显具有13.1%的更高效率。它还表现出约90%的优异光降解效率。研究发现,该纳米复合材料的效率高于纯SnS和MWCNT。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2712/12218360/6a32887484bf/41598_2025_7281_Fig1_HTML.jpg

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