Qin Guoqiang, Lv Xinran, Li Kaili, Yang Zhigang, Sheng Tianqing, Zhang Shuqin, Wei Xuguang, Yu Gang, Yu Jianbo, Song Ruili
School of Materials Science and Engineering, Engineering Research Center of Matamaterials and Microdevices, Shijiazhuang Tiedao University, Shijiazhuang, 050043, China.
State Key Laboratory of Advanced Special Steel, School of Materials Science and Engineering, Shanghai University, Shanghai, 200444, China.
Sci Rep. 2025 Jul 1;15(1):21965. doi: 10.1038/s41598-025-04817-4.
In this study, the effect of Zr elements on Al-10Ce alloys were investigated in terms of the microstructure, mechanical properties at room and high temperatures, and corrosion resistance. Meanwhile, the finite element simulations on tensile fracture was adopted to explain the fracture process of Al-Ce alloys. Results showed that as Zr content increased from 0.05 to 0.15%, the eutectic AlCe phase were gradually coarsened. However, further increase in Zr content led to the refinement and homogenization. Meanwhile, a significant transformation in the morphology of eutectic AlCe from layered to rod-like or bar-like structures happened. Correspondingly, mechanical properties at room temperature such as hardness, tensile strength, and yield strength initially decreased but subsequently increased. The tensile strength and yield strength of the alloys could reach the maximum values of 160 MPa and 96 MPa, respectively, and the elongation of the alloy reached the highest of 14.4%. The yield strength and the tensile strength at high temperature of 300 °C exhibited the highest values of 62.5 Mpa and 74 Mpa, respectively, when the Zr content is 0.05%. Moreover, the corrosion current of the alloys was minimized to 1.158 × 10 µA/cm when the content of Zr was 0.05%, which attributed to the observed optimal microstructural characteristics of the AlCe phase at this concentration. Therefore, it is believed that Al-10Ce-Zr alloys are excellent candidate engineering materials in extreme environment fields.
在本研究中,从微观结构、室温和高温下的力学性能以及耐腐蚀性方面研究了Zr元素对Al-10Ce合金的影响。同时,采用拉伸断裂的有限元模拟来解释Al-Ce合金的断裂过程。结果表明,随着Zr含量从0.05%增加到0.15%,共晶AlCe相逐渐粗化。然而,Zr含量的进一步增加导致细化和均匀化。同时,共晶AlCe的形态发生了从层状到棒状或条状结构的显著转变。相应地,室温下的力学性能如硬度、抗拉强度和屈服强度最初下降但随后上升。合金的抗拉强度和屈服强度分别可达最大值160MPa和96MPa,合金的伸长率最高可达14.4%。当Zr含量为0.05%时,300℃高温下的屈服强度和抗拉强度分别呈现出最高值62.5MPa和74MPa。此外,当Zr含量为0.05%时,合金的腐蚀电流最小化至1.158×10μA/cm²,这归因于在此浓度下观察到的AlCe相的最佳微观结构特征。因此,认为Al-10Ce-Zr合金是极端环境领域中优异的候选工程材料。