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来自植物和动物源的天然蜡作为低压有机场效应晶体管的电介质。

Natural waxes from plant and animal origin as dielectrics for low-voltage organic field effect transistors.

作者信息

Irimia Cristian Vlad, Yumusak Cigdem, Kanbur Yasin, Schimanofsky Corina, Ban Boyuan, Ciganek Martin, Sedlacek Petr, Krajcovic Jozef, D'Orsi Rosarita, Operamolla Alessandra, Brüggemann Oliver, Salinas Yolanda, Petritz Andreas, Stadlober Barbara, Mourya Rahul, Teichert Christian, Langhals Heinz, Sariciftci Niyazi Serdar, Irimia-Vladu Mihai

机构信息

Linz Institute for Organic Solar Cells (LIOS), Institute of Physical Chemistry, Johannes Kepler University Linz Altenberger Str. 69 4040 Linz Austria

Department of Chemistry, Karabük University, Baliklarkayasi Mevkii Karabük 78050 Turkey.

出版信息

J Mater Chem C Mater. 2025 May 29. doi: 10.1039/d5tc01419k.

DOI:10.1039/d5tc01419k
PMID:40606595
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12208171/
Abstract

We demonstrate in this work the practical use of naturally extracted waxes of plant and animal origin, , beeswax, carnauba wax, rice bran wax, lanolin wax, and two shellac waxes as dielectrics in organic field effect transistors (OFETs). We present a thorough characterization of their material properties, processability and film forming characteristic, surface characterization, dielectric investigation and the fabrication of field effect transistors with two classic organic semiconductors, , pentacene and fullerene C. We show that operating voltages as low as 1 V are possible for all the OFETs using blade coating as fabrication method of waxes solubilized in their appropriate solvent, chloroform or -octane. Although in general difficult to process in thin films, we demonstrate in this work the practical applicability of these natural waxes for electronics fabrication.

摘要

在本研究中,我们展示了天然提取的动植物源蜡(蜂蜡、巴西棕榈蜡、米糠蜡、羊毛脂蜡和两种紫胶蜡)在有机场效应晶体管(OFET)中作为电介质的实际应用。我们全面表征了它们的材料特性、可加工性和成膜特性、表面特性、介电性能,并使用两种经典有机半导体(并五苯和富勒烯C)制造了场效应晶体管。我们表明,使用刮刀涂布法将蜡溶解在其合适的溶剂(氯仿或正辛烷)中制备的所有OFET,其工作电压低至1V。尽管这些天然蜡通常难以制成薄膜,但我们在本研究中证明了它们在电子制造中的实际适用性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f776/12208171/3bf429573930/d5tc01419k-f15.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f776/12208171/3bf429573930/d5tc01419k-f15.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f776/12208171/aba96a6c04e7/d5tc01419k-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f776/12208171/32840a3710c1/d5tc01419k-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f776/12208171/5638ff39dff7/d5tc01419k-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f776/12208171/e152cb63f953/d5tc01419k-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f776/12208171/4980489f694d/d5tc01419k-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f776/12208171/7d7de26ecb8c/d5tc01419k-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f776/12208171/d2ca8725939e/d5tc01419k-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f776/12208171/153108a9f969/d5tc01419k-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f776/12208171/b5b7b04aa69b/d5tc01419k-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f776/12208171/b12d7f38ad1e/d5tc01419k-f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f776/12208171/20d7975057bd/d5tc01419k-f14.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f776/12208171/3bf429573930/d5tc01419k-f15.jpg

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