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基于机器视觉的有机物含量自动滴定检测方法

Automatic titration detection method of organic matter content based on machine vision.

作者信息

Zhang Bingjie, Li Meng, Song Qing, Xu Lujian

机构信息

University of Jinan, Jinan, People's Republic of China.

出版信息

R Soc Open Sci. 2025 Jul 2;12(7):250234. doi: 10.1098/rsos.250234.

Abstract

This article proposes an automatic titration algorithm for organic matter content detection based on machine vision, which addresses the disadvantages of high risk factor, strong odour, significant pollution to laboratory environment and slow efficiency of manual titration in organic matter detection. First, by analysing the colour change characteristics during the titration process, machine learning techniques are used to classify the titration speed, and a titration experiment state recognition model is constructed to divide the titration speed into four categories and improve titration efficiency; Second, through a large number of titration experiments to collect relevant data and extract key feature parameters, an efficient titration algorithm based on histogram similarity was designed to accurately identify titration endpoints and improve detection accuracy. This study not only solves the limitations of manual operation in traditional titration methods, but also provides new ideas and methods for the automation and intelligence of chemical titration. The test results showed that the device had a titration error of less than 0.2 ml and was more efficient than manual titration. When comparing the results with manual titration, no statistically significant difference was observed when paired -test was applied at a 95% confidence level. Therefore, it has been confirmed that it has good recognition rate and control accuracy.

摘要

本文提出了一种基于机器视觉的有机物含量检测自动滴定算法,该算法解决了有机物检测中人工滴定危险因素高、气味大、对实验室环境污染严重以及效率低等缺点。首先,通过分析滴定过程中的颜色变化特征,利用机器学习技术对滴定速度进行分类,构建滴定实验状态识别模型,将滴定速度分为四类,提高滴定效率;其次,通过大量滴定实验收集相关数据并提取关键特征参数,设计了一种基于直方图相似度的高效滴定算法,准确识别滴定终点,提高检测精度。本研究不仅解决了传统滴定方法中人工操作的局限性,还为化学滴定的自动化和智能化提供了新的思路和方法。测试结果表明,该装置的滴定误差小于0.2毫升,且比人工滴定更高效。将结果与人工滴定进行比较时,在95%置信水平下进行配对检验时,未观察到统计学上的显著差异。因此,已证实其具有良好的识别率和控制精度。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77a8/12212985/927a48762e08/rsos.250234.f001.jpg

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