Martinez-Baltezar Rodrigo, Martínez-Martínez Carlos M, Medina-Juárez L Alberto, Sánchez-Santacruz Gustavo, Azorín-Nieto Juan
Departamento de Física, Universidad Autónoma Metropolitana-Iztapalapa, Ciudad de México, México.
Luminescence. 2025 Jul;40(7):e70251. doi: 10.1002/bio.70251.
The thermoluminescent (TL) properties of BeO ceramics (Thermalox 995) were investigated under gamma and alpha/gamma irradiation. Glow curves in both cases exhibit three main peaks at 348 ± 1 K, 477 ± 2 K, and 616 ± 1 K. Activation energies for gammainduced peaks are 0.76 ± 0.03 eV, 1.18 ± 0.04 eV, and 1.11 ± 0.02 eV; these increase slightly under alpha/gamma irradiation to 0.81 ± 0.02 eV, 1.22 ± 0.03 eV, and 1.18 ± 0.01 eV. The kinetic orders are close to first order, with slightly higher values observed for the 477 K peak. Based on these parameters, the half-lives of the TL components were calculated. For gamma: 131 s, 1.92 years, and 522 years; and for alpha/gamma: 168 s, 5.07 years, and 2067 years. Fading experiments on five samples showed deviations of less than 10% from theoretical values for the first peak. The half-life also varied with irradiation time: the 477 K peak showed a decreasing trend, while the 616 K peak increased, indicating differences in trap-filling mechanisms. Deconvolution analysis revealed that the second peak (around 477 K) exhibits the most linear dose response under both irradiation types. These results underscore the significance of analyzing half-life behavior to understand the stability and performance of BeO as a dosimetric material under varied irradiation conditions.
研究了氧化铍陶瓷(Thermalox 995)在γ射线和α/γ射线辐照下的热释光(TL)特性。在这两种情况下,热释光曲线均在348±1K、477±2K和616±1K处呈现三个主要峰值。γ射线诱导峰值的激活能分别为0.76±0.03eV、1.18±0.04eV和1.11±0.02eV;在α/γ射线辐照下,这些值略有增加,分别为0.81±0.02eV、1.22±0.03eV和1.18±0.01eV。动力学级数接近一级,477K峰值处的值略高。基于这些参数,计算了热释光成分的半衰期。对于γ射线:131秒、1.92年和522年;对于α/γ射线:168秒、5.07年和2067年。对五个样品进行的衰退实验表明,第一个峰值的偏差与理论值相差不到10%。半衰期也随辐照时间而变化:477K峰值呈下降趋势,而616K峰值上升,表明陷阱填充机制存在差异。去卷积分析表明,在两种辐照类型下,第二个峰值(约477K)表现出最线性的剂量响应。这些结果强调了分析半衰期行为对于理解氧化铍作为剂量测定材料在不同辐照条件下的稳定性和性能的重要性。