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使用纤维和表面处理来提高受硫化矿开采影响的混凝土的耐久性。

Use of fibres and surface treatment to improve the durability of concrete affected by sulphide mining.

作者信息

Davila Jose Miguel, Rodriguez-Gomez Cristian, Sarmiento Aguasanta Miguel

机构信息

Department of Mining, Mechanical, Energy and Construction Engineering, University of Huelva, Avda. Fuerzas Armadas s/n, 21007, Huelva, Spain.

Science and Technology Centre of Huelva (CCTH), University of Huelva, 21007, Huelva, Spain.

出版信息

Sci Rep. 2025 Jul 11;15(1):25090. doi: 10.1038/s41598-025-10855-9.

Abstract

The aim of this research is to evaluate solutions to improve the durability of structural concrete used in sulphide mining. This type of environment is one of the most aggressive conditions in which a concrete structure can be placed, with pH values below 3 and high sulphate contents. These environments cause significant degradation of metallic and structural materials, resulting in mass loss and alteration of mechanical properties, a process that is accelerated by the intervention of acidophilic bacteria. In this work it is proposed to reinforce the concrete by incorporating polypropylene fibres and silica fume and to protect the specimens by applying two types of surface materials, one polyurethane base and the other asphalt base. Several laboratory tests were carried out to evaluate the fundamental mechanical properties and durability of concrete, including tensile and compressive strength tests In addition, Slake tests were carried out to analyse the degradation of different fragments, water permeability tests and pressure sandblasting tests to measure the behaviour of the concrete against abrasion. The results confirm an increase in the tensile strength of fibre-reinforced concrete of about 8%, while the use of both types of surface materials has been shown a zero water penetration depth, while at the same time significantly improves the performance against impact degradation and abrasion with a reduction in weight loss that obtained in the reference samples with Slake test which is reduced to only 0.45% with surface treatment with polyurethane, 1.01% with asphaltic treatment and 2.48% with fibres, and even no weight loss in the sandblasting tests on the samples treated with asphalt material.

摘要

本研究的目的是评估提高硫化矿开采中使用的结构混凝土耐久性的解决方案。这种环境是混凝土结构可能所处的最具侵蚀性的条件之一,pH值低于3且硫酸盐含量高。这些环境会导致金属和结构材料的显著降解,导致质量损失和力学性能改变,嗜酸性细菌的介入会加速这一过程。在这项工作中,建议通过掺入聚丙烯纤维和硅灰来增强混凝土,并通过应用两种表面材料来保护试样,一种是聚氨酯基,另一种是沥青基。进行了多项实验室测试以评估混凝土的基本力学性能和耐久性,包括拉伸和抗压强度测试。此外,进行了崩解试验以分析不同碎片的降解情况,进行了水渗透性试验和喷砂试验以测量混凝土的耐磨性能。结果证实,纤维增强混凝土的抗拉强度提高了约8%,而使用两种表面材料均显示水渗透深度为零,同时显著提高了抗冲击降解和耐磨性能,通过崩解试验,参考样品的重量损失减少,聚氨酯表面处理的样品重量损失仅降至0.45%,沥青处理的样品为1.01%,纤维处理的样品为2.48%,甚至用沥青材料处理的样品在喷砂试验中没有重量损失。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27d6/12254407/20015839586e/41598_2025_10855_Fig1_HTML.jpg

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