Experimental Evaluation and Thermodynamic Analysis of Magnetic FeO@La-Zr-MOFs for Highly Efficient Fluoride and Phosphate Removal.

Phosphate and fluoride ions are common water pollutants whose presence and excessive discharge cause potential hazards to the environment and human health. MOF materials commonly used to remove phosphate and fluoride ions are usually in powder form, with low recovery during regeneration. Herein, to address these issues, FeO@La-Zr-MOFs magnetic composites for phosphate and fluoride removal were fabricated by means of the hydrothermal method. The adsorption properties of the adsorbent were systematically assessed by means of adsorption experiments. The magnetic FeO@La-Zr-MOFs exhibited a magnetic recovery efficiency of 93%, and they could maintain outstanding adsorption performance at a broad range of pH values and superior selectivity for phosphate and fluoride ions. The adsorption process conformed to the Langmuir isotherm and pseudo-second-order models, indicating that it was dominated by monomolecular chemisorption. Further characterization of the FeO@La-Zr-MOFs before and after adsorption and kinetic thermodynamic investigation revealed that the elimination mechanism of phosphate and fluoride ions by FeO@La-Zr-MOFs includes ion exchange, electrostatic interactions, and surface complexation. This study demonstrates that magnetic reusable FeO@La-Zr-MOFs composites have great promise for phosphate and fluoride removal and recovery.