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新型磁性非均相纳米结构钯催化剂的制备与表征及其在铃木反应和施蒂勒反应中的催化研究

Preparation and identification of new magnetic heterogeneous nanostructural palladium catalyst, and its catalytic study in Suzuki and Stille reactions.

作者信息

Safari Sahar, Ghorbani-Choghamarani Arash, Monem Arezo, Rezaeivala Majid

机构信息

Department of Organic Chemistry, Faculty of Chemistry and Petroleum Sciences, Bu-Ali Sina University, Hamedan, Iran.

Department of Chemical Engineering, Hamedan University of Technology, Hamedan, Iran.

出版信息

Sci Rep. 2025 Jul 12;15(1):25272. doi: 10.1038/s41598-025-10438-8.

DOI:10.1038/s41598-025-10438-8
PMID:40652078
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12255767/
Abstract

This study designed and synthesized a new magnetic Palladium-containing nanocatalyst supported on ZnFeO (zinc ferrite magnetic nanoparticles). TGA, TEM, FT-IR, EDS, XRD, BET, VSM, X-ray mapping, ICP-OES, and SEM techniques are used to analyze the structure and magnetic properties of this nanomagnetic material. The synthesized heterogeneous catalyst (ZnFeO@SiO@CPTMS@PYA-Pd) revealed remarkable properties, including high thermal and chemical stability, low toxicity, and efficient reusability. The catalytic behavior of ZnFeO@SiO@CPTMS@PYA-Pd was studied in very well-known C-C bond formation reactions (i.e., Stille and Suzuki cross-coupling reactions), and substituted biphenyls were achieved with good to high yield and conversion. The catalyst demonstrated exceptional performance in cross-coupling reactions, achieving yields of up to 96% for Suzuki reactions (100 min reaction time) and 94% for Stille reactions (120 min reaction time) under optimized conditions. The ZnFeO@SiO@CPTMS@PYA-Pd was recovered easily by an external magnet and reused for five consecutive runs while maintaining with negligible decreases in its activity in described coupling reactions.

摘要

本研究设计并合成了一种负载在ZnFeO（锌铁氧体磁性纳米颗粒）上的新型含钯磁性纳米催化剂。采用热重分析（TGA）、透射电子显微镜（TEM）、傅里叶变换红外光谱（FT-IR）、能谱分析（EDS）、X射线衍射（XRD）、比表面积分析（BET）、振动样品磁强计（VSM）、X射线映射、电感耦合等离子体质谱（ICP-OES）和扫描电子显微镜（SEM）技术来分析这种纳米磁性材料的结构和磁性。合成的多相催化剂（ZnFeO@SiO@CPTMS@PYA-Pd）具有显著的性能，包括高热稳定性和化学稳定性、低毒性以及高效的可重复使用性。在非常著名的C-C键形成反应（即Stille和Suzuki交叉偶联反应）中研究了ZnFeO@SiO@CPTMS@PYA-Pd的催化行为，以良好至高的产率和转化率得到了取代联苯。该催化剂在交叉偶联反应中表现出优异的性能，在优化条件下，Suzuki反应（反应时间100分钟）的产率高达96%，Stille反应（反应时间120分钟）的产率高达94%。ZnFeO@SiO@CPTMS@PYA-Pd可通过外部磁铁轻松回收，并连续重复使用五次，同时在所述偶联反应中其活性的降低可忽略不计。

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本文引用的文献

[1]
Mixed Carboxylate Ligands Bridging Tetra-Pr-Encapsulated Antimonotungstate: Syntheses, Structure, and Catalytic Activity for Imidazoles Synthesis.

Inorg Chem. 2024-12-2

[2]
Dendrimer templated ionic liquid nanomagnetic for efficient coupling reactions.

Sci Rep. 2024-10-23

[3]
The Assembly of Cerium(III)-Containing Silicotungstate with Lewis Acid-Base Sites Enables the Selective -Alkenylation of Oxindole.

Inorg Chem. 2024-10-14

[4]
FeO@gCN@Thiamine: a novel heterogeneous catalyst for the synthesis of heterocyclic compounds and microextraction of tebuconazole in food samples.

Sci Rep. 2024-9-14

[5]
Dy/Ho-encapsulated tartaric acid-functionalized tungstoantimonates: heterogeneous catalysts for isoindolinone synthesis.

Chem Commun (Camb). 2024-9-26

[6]
FeO@SiO@NTMPThio-Cu: a sustainable and eco-friendly approach for the synthesis of heterocycle derivatives using a novel dendrimer template nanocatalyst.

Sci Rep. 2024-7-29

[7]
Palladium anchored to BisPyP@bilayer-SiO@NMP organic-inorganic hybrid as an efficient and recoverable novel nanocatalyst in suzuki and stille C-C coupling reactions.

Sci Rep. 2024-4-18

[8]
Indirect Electrocatalysis S─N/S─S Bond Construction by Robust Polyoxometalate Based Foams.

Adv Mater. 2023-10

[9]
Green synthesis of ZnFeO nanoparticles using plant extracts and their applications: A review.

Sci Total Environ. 2023-5-10

[10]
Recent advances in Metal Organic Framework (MOF)-based hierarchical composites for water treatment by adsorptional photocatalysis: A review.

Environ Res. 2023-4-1

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