Martin M Guadalupe, Clavero Lucio R, Gomez Camila S, Aiassa Virginia, Lázaro-Martínez Juan M, Martín Sandra E, Uberman Paula M, Budén María E
Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Haya de la Torre y Medina Allende Córdoba Córdoba X5000HUA Argentina
Instituto de Investigaciones en Fisicoquímica, INFIQC-CONICET-Universidad Nacional de Córdoba, Haya de la Torre y Medina Allende Córdoba Córdoba X5000HUA Argentina.
RSC Adv. 2025 Jul 11;15(30):24393-24405. doi: 10.1039/d5ra03539b. eCollection 2025 Jul 10.
Photoredox catalysis driven by visible light provides an efficient and environmentally friendly strategy for organic synthesis. In this study, we report a novel heterogeneous photocatalyst developed by immobilizing 1,5-diaminoanthraquinone (DAAQ) onto functionalized silica nanoparticles (SNPs). The photocatalyst was thoroughly characterized using various techniques, including TEM, SEM, UV-vis, FT-IR, ss-NMR, DLS, and XPS. Its photocatalytic performance was assessed in three reaction systems: the dehalogenation of aryl halides, cross-dehydrogenative coupling (CDC) of -aryl-1,2,3,4-tetrahydroisoquinolines, and singlet oxygen generation energy transfer. The SNPs-DAAQ catalyst showed high photocatalytic activity and excellent recyclability, achieving up to 10 cycles. Additionally, the nanomaterial exhibited promising antibacterial properties against . The catalyst's robust performance and potential applications in green chemistry and antibacterial devices highlight its value in designing sustainable synthetic methodologies.
可见光驱动的光氧化还原催化为有机合成提供了一种高效且环保的策略。在本研究中,我们报道了一种通过将1,5-二氨基蒽醌(DAAQ)固定在功能化二氧化硅纳米颗粒(SNPs)上开发的新型非均相光催化剂。使用各种技术对该光催化剂进行了全面表征,包括透射电子显微镜(TEM)、扫描电子显微镜(SEM)、紫外可见光谱(UV-vis)、傅里叶变换红外光谱(FT-IR)、固体核磁共振(ss-NMR)、动态光散射(DLS)和X射线光电子能谱(XPS)。在三个反应体系中评估了其光催化性能:芳基卤化物的脱卤反应、1-芳基-1,2,3,4-四氢异喹啉的交叉脱氢偶联(CDC)反应以及单线态氧生成能量转移反应。SNPs-DAAQ催化剂表现出高光催化活性和出色的可回收性,最多可实现10次循环。此外,该纳米材料对……表现出有前景的抗菌性能。该催化剂的强大性能及其在绿色化学和抗菌装置中的潜在应用突出了其在设计可持续合成方法中的价值。