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可见光吖啶鎓基有机光氧化还原催化在后期合成应用中的研究

Visible-light acridinium-based organophotoredox catalysis in late-stage synthetic applications.

作者信息

Singh Praveen P, Singh Jaya, Srivastava Vishal

机构信息

Department of Chemistry, United College of Engineering & Research Naini Prayagraj 211010 India

Department of Chemistry, LRPG College Sahibabad Gaziabad Uttar Pradesh India.

出版信息

RSC Adv. 2023 Apr 6;13(16):10958-10986. doi: 10.1039/d3ra01364b. eCollection 2023 Apr 3.

DOI:10.1039/d3ra01364b
PMID:37033422
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10077514/
Abstract

The field of photoredox catalysis has been transformed by the use of organic photocatalysts, which give access to re-activities that were previously only possible with transition-metal photocatalysts. Recent advancements in the use of an acridinium photocatalyst in organic synthesis are covered in this review. Both the late-stage functionalization of biorelevant molecules and the activation of inert chemical bonds are explored, with an emphasis on their mechanistic features.

摘要

有机光催化剂的应用改变了光氧化还原催化领域，它能实现一些以前只有过渡金属光催化剂才能达到的反应活性。本文综述了吖啶鎓光催化剂在有机合成中的最新进展。文中探讨了生物相关分子的后期官能团化以及惰性化学键的活化，并着重介绍了它们的机理特点。

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