Li Longfei, Sun Zihao, Yang Mingcheng
Beijing National Laboratory for Condensed Matter Physics and Laboratory of Soft Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China.
School of Physical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China.
Proc Natl Acad Sci U S A. 2025 Jul 22;122(29):e2505010122. doi: 10.1073/pnas.2505010122. Epub 2025 Jul 17.
The confliction between the stable interface in phase-separated active Brownian particles and its negative surface tension, obtained mechanically via the active pressure, has sparked considerable debate about the formula of active surface tension. Based on the intrinsic pressure of active system, we here derive a mechanical expression of active surface tension by calculating the work required to create a differential interface area, while remaining the interfacial profiles of intensive quantities invariant (not considered previously). Our expression yields a significantly positive surface tension that increases with the particle activity, which is further supported by mechanical stability analysis of both steady-state droplet and fluctuating interface. Our work is thus promising to resolve the contradiction related to active surface tension.
相分离活性布朗粒子中稳定界面与其通过活性压力机械获得的负表面张力之间的冲突,引发了关于活性表面张力公式的大量争论。基于活性系统的内禀压力,我们在此通过计算创建微分界面面积所需的功来推导活性表面张力的力学表达式,同时保持强度量的界面分布不变(此前未考虑)。我们的表达式产生了一个显著为正的表面张力,它随粒子活性增加,稳态液滴和波动界面的力学稳定性分析进一步支持了这一点。因此,我们的工作有望解决与活性表面张力相关的矛盾。