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用于增强罗丹明B光催化降解的石墨相氮化碳基复合材料的最新进展:机理、性能及环境应用

Recent advances in graphitic carbon nitride-based composites for enhanced photocatalytic degradation of rhodamine B: mechanism, properties and environmental applications.

作者信息

Zheng Meie, Guo Mengru, Ma Fei, Li Wenwen, Shao Yujia

机构信息

Hubei Key Laboratory of Resource Utilization and Quality Control of Characteristic Crops, College of Life Science and Technology, Hubei Provincial Engineering Research Center of Key Technologies in Modern Paper and Hygiene Products Manufacturing, School of Mechanical Engineering, Research Center of Hubei Small Town Development, Hubei Engineering University Xiaogan 432000 China

出版信息

Nanoscale Adv. 2025 Jun 26. doi: 10.1039/d5na00439j.

Abstract

Graphitic carbon nitride (g-CN), a photocatalyst responsive to visible light, shows remarkable promise for the effective photocatalytic decomposition of organic dyes. This can be attributed to its merits, such as low preparation cost and high stability. The synthetic dye Rhodamine B (RhB) poses serious ecological and health risks because it persists in aquatic environments because of its resistance to natural degradation. The purpose of this paper is to review the current breakthroughs in g-CN modification. The main methods include surface functionalization and morphological engineering to increase visible light acquisition, suppress charge recombination, enhance visible-light absorption and optimize photocatalytic efficiency. An in-depth analysis of the key factors affecting the degradation of RhB by g-CN, including the catalyst dosage, solution pH, dye concentration, light conditions, catalyst stability and reusability, was performed. Mechanistic aspects highlight the key role of reactive oxygen species as well as interfacial charge transfer pathways in the system. Finally, to advance the use of g-CN-based photocatalysts in sustainable environmental remediation, future directions for material optimization and industrial applications are proposed.

摘要

石墨相氮化碳(g-CN)是一种对可见光有响应的光催化剂,在有效光催化分解有机染料方面显示出巨大潜力。这可归因于其诸多优点,如制备成本低和稳定性高。合成染料罗丹明B(RhB)会造成严重的生态和健康风险,因为它由于抗自然降解而在水生环境中持续存在。本文的目的是综述g-CN改性方面的当前突破。主要方法包括表面功能化和形态工程,以增加可见光捕获、抑制电荷复合、增强可见光吸收并优化光催化效率。对影响g-CN降解RhB的关键因素进行了深入分析,包括催化剂用量、溶液pH值、染料浓度、光照条件、催化剂稳定性和可重复使用性。机理方面突出了活性氧物种以及系统中界面电荷转移途径的关键作用。最后,为了推动基于g-CN的光催化剂在可持续环境修复中的应用,提出了材料优化和工业应用的未来方向。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/47a2/12323849/c7409427d28d/d5na00439j-f1.jpg

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