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芝麻饼粕美拉德反应产物关键前体肽及风味增强成分的全成分分析

Inclusive analysis of key precursor peptides and flavor enhancing components of sesame cake meal maillard reaction products.

作者信息

Lou Peng-Xiang, Zhang Jian-Guo, Zhang Wang-Wei, Thakur Kiran, Zhang Yinping, Wei Zhao-Jun

机构信息

School of Food and Biological Engineering, Hefei University of Technology, Hefei 230009, People's Republic of China.

School of Biological Science and Engineering, Specialty Food Nutrition and Health Innovation Team of Ningxia Hui Autonomous Region, North Minzu University, Yinchuan 750021, People's Republic of China.

出版信息

Food Chem X. 2025 Jul 8;29:102755. doi: 10.1016/j.fochx.2025.102755. eCollection 2025 Jul.

Abstract

Our study investigated the flavor-enhancing attributes of Maillard reaction products (MRPs) derived from sesame cake meal digest. Taste dilution analysis (TDA) revealed that peptide-MRPs significantly enhanced flavor depth, umami intensity, and flavor continuity. LC-MS/MS analysis identified 30 distinct peptides in the sesame cake meal digest after the Maillard reaction. Among them, AHSVIY, PELIR, SLTIP, and ILAFPA accounted for 46.17 %, 7.37 %, 3.78 % and 3.72 % of the total peptide content, respectively. The formation of sulfur-containing compounds with meaty taste mainly relied on cysteine, while peptides reacted highly to oxygenated heterocyclic compounds and amino acids. We identified 12 flavor dilutions, including 2-methyl-3-furan mercaptan, benzaldehyde, 2,3-dimethylpyrazine, pyrrole, furfuryl mercaptan, 2,4-dimethylbenzaldehyde, 1-(2-furylmethyl)-1H-pyrrole, guaiacol, thymol, eugenol, pyrazine, and 5-methyl-2-thiophene carboxaldehyde. Our results demonstrate key peptides and flavor compounds in sesame cake meal-derived MRPs, have the potential to serve as natural flavor enhancers. These findings provide valuable insights into the flavor and nutritional properties of sesame byproducts.

摘要

我们的研究调查了芝麻饼粕消化物衍生的美拉德反应产物(MRPs)的风味增强特性。风味稀释分析(TDA)表明,肽-MRPs显著增强了风味深度、鲜味强度和风味连续性。液相色谱-串联质谱(LC-MS/MS)分析在美拉德反应后的芝麻饼粕消化物中鉴定出30种不同的肽。其中,AHSVIY、PELIR、SLTIP和ILAFPA分别占总肽含量的46.17%、7.37%、3.78%和3.72%。含肉味含硫化合物的形成主要依赖于半胱氨酸,而肽对含氧杂环化合物和氨基酸反应强烈。我们鉴定出12种风味稀释物,包括2-甲基-3-呋喃硫醇、苯甲醛、2,3-二甲基吡嗪、吡咯、糠硫醇、2,4-二甲基苯甲醛、1-(2-糠基甲基)-1H-吡咯、愈创木酚、百里酚、丁香酚、吡嗪和5-甲基-2-噻吩甲醛。我们的研究结果揭示了芝麻饼粕衍生的MRPs中的关键肽和风味化合物,有潜力作为天然风味增强剂。这些发现为芝麻副产品的风味和营养特性提供了有价值的见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b32c/12274689/9ffd323c8e2a/ga1.jpg

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