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用回收阴极射线管玻璃增强的柔性硅橡胶复合材料的γ射线屏蔽能力

Gamma ray shielding capability of flexible silicone rubber composites reinforced with recycled CRT glasses.

作者信息

Elsayed Doaa A, Elsafi Mohamed, Abdel-Gawad Esraa H, Al-Balawi Shoaa M, Sayyed M I, Saleh Ibrahim H

机构信息

Environmental Studies Department, Institute of Graduate Studies and Research, Alexandria University, Alexandria, 21511, Egypt.

Physics Department, Faculty of Science, Alexandria University, Alexandria, 21511, Egypt.

出版信息

Sci Rep. 2025 Jul 21;15(1):26458. doi: 10.1038/s41598-025-10920-3.

Abstract

With a focus on extending the horizons of combining electronic waste (e-waste) with different materials for creating efficient, affordable, eco-friendly, and sustainable radiation shielding composites, the present study investigates the radiation shielding performance of different composites made of silicon rubber and e-waste glass. Six samples were prepared by mixing different amounts of powdered cathode ray tube (CRT) glass (0-50%) with silicon rubber (100-50%). The linear attenuation coefficients (LAC's) of the prepared samples were experimentally measured using a high-purity germanium detector and varying energy gamma sources. Other radiation shielding parameters such as mass attenuation coefficient (MAC), transmission factor (TF), mean free path (MFP), half value layer (HVL) and radiation attenuation ratio (RAR) were calculated. The sample with the highest CRT content (SR-CRT-50) showed the highest efficiency superior to the rest of the prepared samples with maximum LAC (2.051 cm), maximum MAC (1.1890 cm/g), minimum HVL (0.338 cm), and minimum TF (0.357) at the lowest energy level of 0.060 MeV. The additive of waste CRT glass to the matrix also improve the mechanical and thermal properties of composites, and accordingly the weight loss at about 620 ± 15 °C was 70.09%, 53.17%, and 32.37% for SR-CRT-0, SR-CRT-30, and SR-CRT-50, respectively. Clearly, this study demonstrated that adding waste CRT glass to the silicone rubber polymer increased its performance as a shield against ionizing photons.

摘要

本研究聚焦于拓展将电子废物(电子垃圾)与不同材料相结合以制造高效、经济、环保且可持续的辐射屏蔽复合材料的领域,对由硅橡胶和电子垃圾玻璃制成的不同复合材料的辐射屏蔽性能进行了研究。通过将不同量的粉末状阴极射线管(CRT)玻璃(0 - 50%)与硅橡胶(100 - 50%)混合制备了六个样品。使用高纯锗探测器和不同能量的伽马源对制备样品的线性衰减系数(LAC)进行了实验测量。计算了其他辐射屏蔽参数,如质量衰减系数(MAC)、传输因子(TF)、平均自由程(MFP)、半值层(HVL)和辐射衰减率(RAR)。在最低能量水平0.060 MeV下,CRT含量最高的样品(SR - CRT - 50)表现出最高的效率,优于其他制备样品,其具有最大LAC(2.051 cm)、最大MAC(1.1890 cm/g)、最小HVL(0.338 cm)和最小TF(0.357)。将废弃CRT玻璃添加到基体中还改善了复合材料的机械和热性能,相应地,SR - CRT - 0、SR - CRT - 30和SR - CRT - 50在约620 ± 15°C时的重量损失分别为70.09%、53.17%和32.37%。显然,本研究表明向硅橡胶聚合物中添加废弃CRT玻璃提高了其作为电离光子屏蔽材料的性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6cc3/12280199/989efb59b1a4/41598_2025_10920_Fig1_HTML.jpg

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