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海藻酸钠-赤泥微球部分替代标准砂对水泥砂浆性能影响的研究

Research on the Effect of Calcium Alginate-Red Mud Microspheres on the Performance of Cement Mortar by Partially Replacing Standard Sand.

作者信息

Liu Ruizhuo, Lin Zibo, Fan Shencheng, Cheng Yao, Li Yuanyang, Li Jinsheng, Zou Haiying, Chen Yongsi, Zheng Liting, Li Jing

机构信息

School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China.

Key Laboratory of New Low-Carbon Green Chemical Technology, Education Department of Guangxi Zhuang Autonomous Region, Nanning 530004, China.

出版信息

Materials (Basel). 2025 Jul 15;18(14):3326. doi: 10.3390/ma18143326.

Abstract

With the depletion of river sand resources and increasing environmental concerns, the development of alternative materials has become an urgent need in the construction industry. Waste concrete and non-waste concrete materials have been widely studied as alternatives to river sand. Although recycled concrete fine aggregates are close to natural sand in terms of mechanical properties, their surface cement adheres and affects the performance of cement, whereas non-recycled concrete fine aggregates perform superiorly in terms of ease of use and compressive properties, but there are challenges of supply stability and standardization. Red mud, as an industrial waste, is a potential alternative material due to its stable supply and high alkaline characteristics. In this paper, a new method is proposed for utilizing the cross-linking reaction between sodium alginate and calcium chloride by the calcium alginate-red mud microsphere preparation technique and the surface modification of red mud to enhance its bonding with cement. The experimental results showed that the mechanical properties of CMC-RM-SiO-2.5% were improved by 13.9% compared with those of the benchmark cement mortar, and the encapsulation of red mud by calcium alginate significantly reduced the transfer of hazardous elements in red mud.

摘要

随着河砂资源的枯竭以及环境问题日益受到关注,开发替代材料已成为建筑业的迫切需求。废混凝土和非废混凝土材料作为河砂的替代品已得到广泛研究。尽管再生混凝土细骨料在力学性能方面接近天然砂,但其表面附着的水泥会影响水泥性能,而非再生混凝土细骨料在易用性和抗压性能方面表现更优,但存在供应稳定性和标准化方面的挑战。赤泥作为一种工业废料,因其供应稳定和高碱性特性,是一种潜在的替代材料。本文提出了一种利用海藻酸钠与氯化钙之间的交联反应,通过海藻酸钙 - 赤泥微球制备技术和赤泥表面改性来增强其与水泥粘结性的新方法。实验结果表明,与基准水泥砂浆相比,CMC - RM - SiO - 2.5%的力学性能提高了13.9%,海藻酸钙对赤泥的包裹显著减少了赤泥中有害元素的迁移。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a5e1/12298050/16cfb9c0d581/materials-18-03326-g001.jpg

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