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["核酸液晶微相的圆二色光谱中的“外部发色团”和强吸收带"]

["External chromophores" and intensive bands in circular dichroism spectra of liquid-crystalline microphases of nucleic acids].

作者信息

Evdokimov Iu M, Salianov V I, Akimenko N M, Chel'tsov P A, Palumbo M

出版信息

Biofizika. 1985 Nov-Dec;30(6):948-54.

PMID:4074762
Abstract

From the analysis of CD-spectra of liquid crystalline microphases formed from DNA molecules in complexes with "external chromophores" requirements are formulated for the compounds to be used in revealing peculiarities of spatial structure of nucleic acids liquid crystalline microphases. These requirements satisfied it is possible to record the CD-spectra having intensive bands in the regions of chromophores absorption. These bands prove the helical pattern of the spatial structure of nucleic acid liquid crystalline microphase.

摘要

通过对由DNA分子与“外部发色团”形成的液晶微相的圆二色光谱进行分析,提出了用于揭示核酸液晶微相空间结构特性的化合物的要求。满足这些要求时,就有可能记录在发色团吸收区域具有强吸收带的圆二色光谱。这些吸收带证明了核酸液晶微相空间结构的螺旋模式。

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